Bis[3,5-di-fluoro-2-(pyridin-2-yl)phen-yl](4,4'-di-meth-oxy-2,2'-bi-pyridine)-iridium(III) hexa-fluorido-phosphate.

The title cyclo-metalated distorted octa-hedral iridium complex, [Ir(CHFN)(CHNO)]PF, exhibits elongated Ir-N bonds to the dimeth-oxy bi-pyridine ligand [2.128 (3) and 2.136 (3) Å] where these nitro-gen atoms are to the Ir-C bonds of the two cyclo-metalating di-fluoro-phenyl-pyridine ligands.