Magnetic Polyamide Nanocomposites for the Microextraction of Benzophenones from Water Samples.

In this article, the influence of the monomers on the extraction efficiency and the effect of the addition of surfactants during the synthesis have also been considered. The sorption capacity of the resulting nanocomposites has been evaluated, in the dispersive micro-solid phase extraction format, by determining that of six benzophenones in water using ultra performance liquid chromatography (UPLC) combined with photodiode array detection. Under the optimum conditions, the limits of detection were in the range of 0.

Recycling polymer residues to synthesize magnetic nanocomposites for dispersive micro-solid phase extraction.

The ubiquitous presence of plastics, an obvious consequence of their usefulness and low price, has turned them into a problem of environmental and safety concern. The new plastic economy, an initiative recently launched by the World Economic Forum and Ellen MacArthur Foundation, with analytical support from McKinsey & Company, promotes a change in the use of plastic worldwide around three main pillars: redesign, reusing and recycling. Recycled plastics, with the aim of extending their life spam, can be used to synthesize materials for analytical purposes.

Determination of propranolol and carvedilol in urine samples using a magnetic polyamide composite and LC-MS/MS.

Aim: β-blockers are compounds that bind with adrenoreceptors hindering their interaction with adrenalin and noradrenalin. They are clinically relevant and they are also used in some sport as doping agents.

Results: A new method based on the combination of dispersive micro-solid phase extraction and LC-MS/MS has been developed to determine propranolol and carvedilol in urine samples.

Polymer-nanoparticles composites in bioanalytical sample preparation.

The term composite refers to a class of synthetic materials made from different constituents which exhibit final properties which are different from those of the individual components. Composites have been extensively used in the sample treatment context as sorbents since the resulting solid presents better extraction efficiency. In this realm, polymeric nanocomposites are raised as a powerful alternative.

Octadecyl functionalized core-shell magnetic silica nanoparticle as a powerful nanocomposite sorbent to extract urinary volatile organic metabolites.

In this present study, magnetic Fe3O4@SiO2 nanoparticles (MNPs) functionalized with octadecyl groups (Fe3O4@SiO2-C18 NPs) were synthesized, characterized and employed, for the first time, as powerful nanosorbent to extract endogenous volatile organic metabolites (EVOMs) namely, hexanal, heptanal, decanal, benzaldehyde, 4-heptanone, 5-methyl-2-furfural and phenol, described as potential biomarkers of cancer, from human urine. By using co-precipitation, surface modification methods, the carbon-ferromagnetic nanocomposite was synthesized and characterized by infrared spectrum (IR) and transmission electron microscopy (TEM). By coupling with gas chromatography-mass spectrometry (GC-qMS), a reliable, sensitive and cost-effective method was validated.

Magnetic nanoparticles-nylon 6 composite for the dispersive micro solid phase extraction of selected polycyclic aromatic hydrocarbons from water samples.

In this article, the easy synthesis of magnetic nanoparticles-nylon 6 composite is presented, characterized and applied in the microextraction field. The one-step synthesis of the composite is performed by a solvent changeover playing with the different solubility of the polymeric network in formic acid and water. The new material has been characterized by different techniques including infrared spectroscopy, transmission and scanning microscopy.

Hybridization of commercial polymeric microparticles and magnetic nanoparticles for the dispersive micro-solid phase extraction of nitroaromatic hydrocarbons from water.

In this article, the combination of commercial polymeric microparticles (OASIS MCX) and cobalt ferrite nanoparticles is evaluated in dispersive micro-solid phase extraction (D-μSPE) for the determination of six nitroaromatic hydrocarbons in water. The high affinity of the polymeric material toward the target analytes as well as the magnetic behavior of cobalt ferrite nanoparticles are combined in a synergic way to developed an efficient and simple D-μSPE approach. The sorptive performance of the hybrid material is compared with that most usual sorbents and the effect of its synthesis steps on the extraction capability is also evaluated in depth.