Synthesis of 5-hydroxymethylfurfural from glucose, fructose, cellulose and agricultural wastes over sulfur-doped peanut shell catalysts in ionic liquid.

In this study, waste peanut shells were sulfur-impregnated and used as acid catalysts in the presence of an ionic liquid for the conversion of fructose, glucose, and cellulose into 5-hydroxymethylfurfural, a useful chemical intermediate for biofuel production. Effects of sulfur-doping duration (1 h and 5 h), solvent type and proportion, reaction temperature (130 °C, 140 °C, and 150 °C), time (30-240 min), catalyst-to-substrate ratio (1-2.5 m/m), and agricultural residue (peanut shell, Canada wheat straw, water hyacinth, stalk, and reed) on HMF yields were investigated.

Electrochemically-driven regeneration of iron (II) enhances Fenton abatement of pesticide cartap.

Cartap is a carbamate insecticide intended to protect crops such as rice, tea, and sugarcane. Cartap in the environment presents a serious threat to non-target organisms through direct exposure or via biomagnification. Electro-assisted Fenton technology taps the potential of Fenton reagents to degrade cartap.