In this study, two novel chemosensors containing dihydropyridine fragment namely; (2E, 2E')-1,1'-(2,6-dimethyl-1,4-dihydropyridine-3,5-diyl)bis(3-(4-(dimethylamino)phenyl)prop-2-en-1-one) (1), (2E,2E',4E,4E')-1,1' -(2,6-dimethyl-1,4-dihydropyridine-3,5-diyl)bis(5-(4-(dimethylamino)phenyl)penta-2,4-dien-1-one) (2) have been synthesized and characterized. The solvatochromic behavior was explored in different solvents of various polarities. The visual detection, as well as UV-Vis and fluorescence measurements were carried out to explore the colorimetric and optical sensing properties of the investigated chemosensors towards various metal ions such as Al, Cr, Mn, Fe, Co, Ni, Cu, Mg, Hg and Zn.
View Article and Find Full Text PDFCellulose was extracted from mango fibers and subjected to acid hydrolysis to obtain a nanofiber. Two morphological structures based on the polylactic acid (PLA)/nanocellulose (NC) combination have been synthesized and FeO NPs (M) are incorporated into both combinations. The first formulation is obtained by blending technique (PLA/M-NC) and the second formulation is obtained by self-assembly of grafted copolymer (M-PLA-co-NC).
View Article and Find Full Text PDFHerein, we report on developing a facile synthetic route for reusable nanocatalysts based on a combination of the supermagnetic properties of magnetite with the unique optical and catalytic properties of noble metal hybrid nanomaterials. We compare two different synthetic methods, to find out which is best from synthetic and application points of view, for the synthesis of FeO and FeO@M (M = Ag or Au) core-shell hybrid nanostructures. The two different single-step synthetic methods are: thermal decomposition and hydrothermal.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2018
Platinum/silver (Pt@Ag) and palladium/silver (Pd@Ag) core/shell NPs have been synthesized in two steps reaction using the citrate method. The progress of nanoparticle formation was followed by the UV/Vis spectroscopy. Transmission electron microscopy revealed spherical shaped core/shell nanoparticles with average particle diameter 32.
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