Insights into the adsorption of emerging organic contaminant by low-cost readily separable modified jute fiber.

A high-efficiency biosorbent based on the low-priced jute fiber was developed, characterized, and applied to remove the emerging organic contaminant diclofenac from aqueous solutions. Jute fiber was treated by NaOH (named AJF) followed by grafting different amounts of trimethyl[3-(trimethoxysilyl) propyl] ammonium chloride (named AJF-TTSAC). The composition, morphology, porosity, and adsorption features of the neat and modified jute fiber were evaluated and compared.

Rapid adsorption of benzotriazole onto oxidized carbon cloth as an easily separable adsorbent.

A commercial carbon cloth (CC) was oxidized by HNO acid and the features of the plain and oxidized CC were evaluated. The results of characterization illustrated that HNO oxidization duplicated the oxygen-containing functional groups and the surface area of the CC. The adsorption performance of the plain and oxidized CC (Oxi-CC) toward benzotriazole (BTR) was compared.

Preparation and characterization of chemically cross-linked zwitterionic copolymer hydrogel for direct dye and toxic trace metal removal from aqueous medium.

In this work, a zwitterionic copolymer hydrogel with adsorption affinity toward anionic dye and cationic trace metal was prepared by a free radical copolymerization of cationic ([3-(methacryloylamino)propyl] trimethylammonium chloride (MPTC)) and anionic (sodium 4-vinylbenzenesulfonate (SVBS)) monomers. Bis[2-(methacryloyloxy)ethyl] phosphate was used as a cross-linker and its effect on the adsorption properties of the prepared hydrogel was evaluated. The prepared materials were characterized by FTIR, XRD, SEM, EDX, and N adsorption at 77 K analysis.

One-Step Room-Temperature Synthesis of Bimetallic Nanoscale Zero-Valent FeCo by Hydrazine Reduction: Effect of Metal Salts and Application in Contaminated Water Treatment.

The effect of initial salt composition on the formation of zero-valent bimetallic FeCo was investigated in this work. Pure crystalline zero-valent FeCo nanoparticles (NPs) were obtained using either chloride or nitrate salts of both metals. Smaller NPs can be obtained using nitrate salts.

Simultaneous decolorization of anionic and cationic dyes by 3D metal-free easily separable visible light active photocatalyst.

To overcome the hard and costly post-treatment separation of ultrathin graphitic carbon nitride nanosheets (UGCN), it was supported on polyurethane foam (PUF). The ratio of PUF/UGCN was optimized for the removal of a mixture of methylene blue (MB) and methyl orange (MO) dyes. The characteristics of the composite photocatalyst and its photocatalytic performance were detailly studied.

Simultaneous removal of Pb and direct red 31 dye from contaminated water using -(2-hydroxyethyl)-2-oxo-2-chromene-3-carboxamide loaded chitosan nanoparticles.

This study reports the preparation of a new material that can remove synthetic dyes and trace metals simultaneously. A new coumarin derivative was synthesized and its chemical structure was inferred from spectral data (FT-IR, H-NMR, C-NMR). Meanwhile, chitosan nanoparticles (CsNPs) were prepared then used as a carrier for two different concentrations of the coumarin derivative (C1@CsNPs and C2@CsNPs).

A dual-functional sulfone biscompound containing 1,2,3-triazole moiety for decolorization and disinfection of contaminated water.

Water decontamination from toxic dyes and pathogenic microorganisms is critical for life on Earth. Herein, we report the synthesis of sulfone biscompound containing 1,2,3-triazole moiety and evaluation of its dye decolorization and biocidal and disinfection efficiencies. The decolorization efficiency was tested under different experimental conditions, while the biocidal action was examined against various types of waterborne pathogens, and the disinfection of some pathogenic microbes was executed in artificially contaminated water.

Multi-exposure human health risks assessment of trihalomethanes in drinking water of Egypt.

The present study aims to assess the probable lifetime cancer and non-cancer risks of exposure to the trihalomethanes in Egypt's drinking water through ingestion, dermal contact, and inhalation. A total of 1667 drinking water samples were collected from twenty-three Egyptian governorates over a three-years period. The concentrations of total trihalomethanes ranged between 29.

Multifunctional 3D cationic starch/nanofibrillated cellulose/silver nanoparticles nanocomposite cryogel: Synthesis, adsorption, and antibacterial characteristics.

We report a new 3D nanocomposite cryogel combines the advantages of cationic starch (Cs), nanofibrillated cellulose (NFC) and silver nanoparticles (Ag NPs). Cs was the main component of the cryogel while NFC was used as a filling agent to enhance the mechanical properties of the produced cryogel. Both Cs and NFC endow the cryogel with adsorption properties while Ag NPs enhances its antibacterial properties.

Hazardous inorganic disinfection by-products in Egypt's tap drinking water: Occurrence and human health risks assessment studies.

This study is the first that monitored the presence and levels of chlorite, chlorate and bromate in tap drinking water of Egypt. Three hundred and eight samples were collected from 22 governorates across Egypt and were analyzed using a standardized ion chromatography method. Forty-seven samples were contaminated by one or more of the inorganic disinfection by-products (DBPs) and only 12 samples exceeded the admissible maximum contamination levels (MCLs).

BiO-BiFeO Glass-Ceramic: Controllable β-/γ-BiO Transformation and Application as Magnetic Solar-Driven Photocatalyst for Water Decontamination.

Glass and glass-ceramic materials containing photoactive and magnetic crystalline phases were prepared from FeO and BiO using the conventional melt method. All samples were characterized in terms of formed phases, morphological analyses, optical properties, and magnetic properties. Formation of the photoactive tetragonal β- and body-centered cubic γ-BiO phases along with the magnetic BiFeO and FeO phases was revealed.

Removal of Hazardous Contaminants from Water by Natural and Zwitterionic Surfactant-modified Clay.

In this study, natural clay (NC) was collected from Saudi Arabia and modified by cocamidopropyl betaine (CAPB) at different conditions (CAPB concentration, reaction time, and reaction temperature). NC and modified clay (CAPB-NC) were characterized using X-ray diffraction, thermogravimetric analysis, Fourier transform infrared spectroscopy, field-emission scanning electron microscopy, and N adsorption at 77 K. The adsorption efficiency of NC and CAPB-NC toward Pb and reactive yellow 160 dye (RY160) was evaluated.

The occurrence and risk assessment of phenolic endocrine-disrupting chemicals in Egypt's drinking and source water.

This is the first nationwide survey of bisphenol A (BPA), methylparaben, ethylparaben, propylparaben, butylparaben, and o-phenylphenol, in Egypt's water. Five hundred fifty-five water samples were collected from source water (SW, 109 samples) and drinking water (DW, 446 samples) of twenty-three Egyptian governorates. These chemicals were determined by direct ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) analysis of a filtered aliquot of samples.

Impact of support characteristics and preparation method on photocatalytic activity of TiO/ZSM-5/silica gel composite photocatalyst.

Titanium dioxide (Degussa P25) was supported onto two different aluminosilicate zeolites (ZSM-5) and anchored on three silica gels using two separate preparation methods to study the effect of the catalyst components and the preparation method on the photoactivity of composite catalysts. The photoactivity was investigated by tracking phenol disappearance in a batch UVA light-emitting diode reactor. An easily separable photocatalyst with higher photoactivity than commercial Degussa P25 was developed using Degussa P25, ZSM-5 (SiO/AlO = 280) and silica gel (particle size 0.

Synthesis, characterization and adsorption properties of microcrystalline cellulose based nanogel for dyes and heavy metals removal.

Recently, naturally occurring biopolymers have attracted the attention as potential adsorbents for the removal of water contaminants. In this work, we present the development of microcrystalline cellulose (MCC)-based nanogel grafted with acrylamide and acrylic acid in the presence of methylene bisacrylamide and potassium persulphate as a crosslinking agent and initiator, respectively. World-class facilities such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), surface analysis, field emission scanning electron microscopy (FE-SEM), high resolution transmission electron microscopy (HR-TEM) and zeta sizer were used to characterize the synthesized MCC based nanogel.

Photocatalytic ozonation of pesticides in a fixed bed flow through UVA-LED photoreactor.

In this study, a fixed bed flow through UVA-LED photoreactor was used to compare the efficiency of ozone, photocatalysis and photocatalysis-ozone degradation, and mineralization of two pure pesticides, 2,4-dichlorophenoxyacetic acid (2,4-D) and 2-methyl-4-chlorophenoxyacetic acid (MCPA), and a commercial one, Killex®. For the degradation of the parent compounds, ozone-based processes were more effective. While for mineralization, photocatalytic processes were more effective.

Preparation and characterization of humic acid-carbon hybrid materials as adsorbents for organic micro-pollutants.

The present work involves the preparation of novel adsorbent materials by the insolubilization and hybridization of humic acid (HA) with carbon. The prepared materials were characterized by N2 adsorption, elemental analysis, Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, solid-state (13)C cross polarization magic angle spinning nuclear magnetic resonance, and low-field nuclear magnetic resonance (NMR) relaxometry on wetted samples. The water solubility of these materials and the lack of effect of oxidants were also confirmed.

Some observations on the development of superior photocatalytic systems for application to water purification by the "adsorb and shuttle" or the interphase charge transfer mechanisms.

Adsorb and shuttle (A/S) and interfacial charge transfer are the two major strategies for overcoming recombination in photocatalysis in this era of nanoparticle composites. Their relationships are considered here. A review of key literature is accompanied by a presentation of three new experiments within the overall aim of assessing the relation of these strategies.

L-carnitine supplementation reduces oocyte cytoskeleton damage and embryo apoptosis induced by incubation in peritoneal fluid from patients with endometriosis.

Objective: To investigate the protective effect of L-carnitine (LC) against deleterious substances present in the peritoneal fluid (PF) of patients with endometriosis, which may affect the oocyte cytoskeleton and embryogenesis.

Design: Experimental study.

Setting: Research embryology laboratory at an academic hospital.