Measurement of Diffusion of Atmospheric Gases in a Liquid Perfluoro Compound by Means of an Optical Technique.

We report on accurate measurements of Fickian diffusion coefficients in binary mixtures consisting of hydrofluoroether (a perfluoro compound of methoxy-nonafluorobutane or HFE-7100) with dissolved atmospheric gases CO, N, and O in the limit of an infinite dilution of the gas. We show that the use of optical digital interferometry (ODI) allows the determination of diffusion coefficients of dissolved gases with relatively small standard uncertainties for this class of experiments. In addition, we illustrate the ability of an optical approach to determine the gas concentration.