This clinical study assessed the effectiveness of diode laser-980 nm as adjuvant in retreatment of failed endodontic cases with chronic periapical lesions on basis of IL-8 expression and postoperative pain when compared to placebo. For 28 patients, the pre-instrumentation periapical samples (S1) were gathered, following retreatment. After chemo-mechanical preparation, post-instrumentation samples (S2) were collected.
View Article and Find Full Text PDFThe present study deals essentially with the establishment of the environmental natural radiation levels in the surveyed area. These will provide base-line information that can be used as a reference to detect and determine the amount and extent of any possible future variation or contamination in the natural radioactivity levels that might occur in the study area due to any potential incidents involving release of nuclear radiation or fallout of nuclear fission products that could affect both terrestrial and atmospheric radioactivity. A map of radiogenic heat production (RHP) was built from the airborne spectral gamma-ray data of North Jabal Maghrabiyah area, central Eastern Desert, Egypt.
View Article and Find Full Text PDFAppropriate heteroatom doping and pore structure optimization are cost-effective technologies to improve the electronic conductivity and ion diffusion kinetics of hard carbons (HCs). Here, we report an ion-catalyzed synthesis of N/O co-doped carbon nanorods (NOCNRs) with abundant hierarchical pores, achieving high-capacity and high-rate Na-ion storage (336 mA h g at 0.1 A g and 196 mA h g at 20.
View Article and Find Full Text PDFSurface oxygen functionalities (particularly C-O configuration) in carbon materials have negative influence on their electrical conductivity and Na storage performance. Herein, we propose a concept from surface chemistry to regulate the oxygen configuration in hierarchically porous carbon nanosheets (HPCNS). It is demonstrated that the C-O/C=O ratio in HPCNS reduces from 1.
View Article and Find Full Text PDFHerein, an efficient biomass utilization is proposed to prepare bio-oil-derived carbon (BODPC) with hierarchical pores and certain H/O/N functionalities for superior Li/Na storage. Kinetic analyses reveal that BODPC has similar behavior in the electrochemical Li and Na storage processes, in terms of physical adsorption (Stage I), chemical redox reactions with surface functionalities (Stage II), and insertion into the graphitic interlayer (Stage III). Promisingly, BODPC exhibits a high reversible specific capacity (1881.
View Article and Find Full Text PDFRaman and electrochemical results reveal that Na adsorbs on the surface/defective sites of N/P-HCNF and inserts randomly into its turbostratic nanodomains in the dilute state without a staged formation, which can facilitate fast Na diffusion kinetics for efficient sodium storage.
View Article and Find Full Text PDFChem Commun (Camb)
August 2021
The introduction of oxygen vacancies (OVs) into NbO can not only provide more active sites for lithium storage but also change the electronic structure of NbO to boost electron/ion transport kinetics. Consequently, the defective NbO exhibits high lithium storage capacity, superior rate capability, and cycling stability.
View Article and Find Full Text PDFA scalable fabrication of 3D hierarchical porous carbon structure (3D-HPC) has been achieved via a simple sonochemical route at different pyrolysis temperatures. It is worth noting that all the 3D-HPC samples possess oxygen-functional groups after activation by KOH and self-doped by nitrogen, which are beneficial to improving their surface wettability as well as increasing the electro-active surface area between the electrode and the surrounding electrolyte, consequently enhancing their electrochemical performance. Remarkably, the resulting carbon sample pyrolyzed at 850 °C (AC-850) possesses a maximum doping level of 2.
View Article and Find Full Text PDFIn the present study, centrifugation was used as a standard harvest method, while chemical flocculation was comparatively used as a cost-effective harvest method for microalgae. Lipid recovery from the centrifuged cells was 17.4%, which significantly increased by flocculation to 20.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
June 2019
Fe and H co-doped PANI/GO (graphene oxide) composites with different iron dopant ratio depending on the starting FeCl (GOPNI-1, GOPNI-2, GOPNI-3 and GOPNI-4) are prepared. The formations of composite samples are investigated by some characterization techniques such as XRD, ATR-IR, UV-Vis spectrophotometer and thermal properties by TGA. While, the Nitrogen adsorption/desorption isotherm for (GOPNI-3) shows high specific surface area 48.
View Article and Find Full Text PDFThe separation and preconcentration of copper(II), lead(II), and cadmium(II) ions on magnetic graphene oxide (MGO) by solid-phase extraction was carried out. Quantitative recovery was obtained by adsorption of analytes on MGO at pH 6 and elution of 3 M HNO3 in 10% acetone. To optimize the presented method, the effects of various parameters-including pH, eluent conditions, and vortex time-were examined.
View Article and Find Full Text PDFToxoplasmosis is a cosmopolitan protozoan disease that has been recorded in a wide range of vertebrate hosts, including humans. In response to the paucity of available data, this study was undertaken to comprehensively establish the seroprevalence of Toxoplasma gondii among various farm animals in different localities of Egypt. The latex agglutination test and TgGRA7-based enzyme-linked immunosorbent assay were used to screen the investigated animals for anti-T.
View Article and Find Full Text PDFBackground: Wheat is considered the most important cereal crop all over the world. The wheat weevil Sitophilus granarius is a serious insect pests in much of the wheat growing area worldwide and is responsible for significant loss of yield. Avidin proteins has been proposed to function as plant defense agents against insect pests.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
February 2015
Nano titanium dioxide TiO2 was synthesized using hydrolysis method then subjected to several characterizations. XRD revealed that the as-prepared sample is pure anatase phase and after calcinations at 500°C for 3 h the crystallinity has increased. The crystallite size calculated by Debye-Scherrer's formula is 8 nm.
View Article and Find Full Text PDFDevelopment of a reliable in vitro plant regeneration procedure for hexaploid bread wheat (Triticum aestivum L.) is a prerequisite for its improvement by genetic transformation. Here, we report the effects of two growth regulators, benzyl adenine (BA) and indole acetic acid (IAA) on callus induction and plant regeneration from scutellum cultures of two commercial bread wheat cultivars: Giza 164 and Sakha 69.
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