Adsorption Affinity of Linear and Aromatic Organic Anions Competing for Cationic Cement Surfaces.

Competitive adsorption of chemical admixtures onto cement is of critical importance in delivering bulk performance requirements of cement slurries employed in constructing high-performing structures, like oil wells. This challenge is complex to investigate, because of the many variables that include the heterogeneity, high pH, and ionic strength of cement fluids; the multiple crystalline phases present in unhydrated and set cement; and the high number of admixtures required to meet performance criteria in commercial operations. The purpose of this study is to relate chemical structures to relative adsorption behavior of admixtures onto cement when present together and classify such interactions as beneficial (synergistic) or detrimental (antagonistic).

Size-dependent impacts of silver nanoparticles on the lifespan, fertility, growth, and locomotion of Caenorhabditis elegans.

The increased bioavailability of nanoparticles engineered for good dispersion in water may have biological and environmental impacts. To examine this issue, the authors assessed the biological effects in nematodes as they relate to exposure to silver nanoparticles (AgNPs) of different sizes at low (1 mg/L Ag), medium (10 mg/L Ag), and high concentrations (100 mg/L Ag). Over multiple generations, the authors found that the smallest particle, at 2 nm, had a notable impact on nematode fertility.

Toxicity of quantum dots and cadmium salt to Caenorhabditis elegans after multigenerational exposure.

To fully understand the biological and environmental impacts of nanomaterials requires studies that address both sublethal end points and multigenerational effects. Here, we use a nematode to examine these issues as they relate to exposure to two different types of quantum dots, core (CdSe) and core-shell (CdSe/ZnS), and to compare the effect to those observed after cadmium salt exposures. The strong fluorescence of the core-shell QDs allowed for the direct visualization of the materials in the digestive track within a few hours of exposure.

t⁴ workshop report. Nanotoxicology: "the end of the beginning" - signs on the roadmap to a strategy for assuring the safe application and use of nanomaterials.

In October 2010, a group of experts met as part of the transatlantic think tank for toxicology (t4) to exchange ideas about the current status and future of safety testing of nanomaterials. At present, there is no widely accepted path forward to assure appropriate and effective hazard identification for engineered nanomaterials. The group discussed needs for characterization of nanomaterials and identified testing protocols that incorporate the use of innovative alternative whole models such as zebrafish or C.