A tris-oxovanadium pyrogallate complex: synthesis, structure, and magnetic and electronic properties.

With the aim of identifying new cation-phenolate complexes, we herein investigated the reactivity of pyrogallol (Hpgal) with vanadium salts. A trimetallic anionic complex was identified, and found to be formed under a broad set of reaction conditions. This complex, with the formula VO(pgal), consists of three oxovanadium(IV) units connected together by three pyrogallate ligands to afford a bowl-shaped species presenting a pseudo 3-fold symmetry axis.

Pairing Cross-Linked Polyviologen with Aromatic Amine Host Structure for Anion Shuttle Rechargeable Batteries.

Electroactive organic compounds could bring new chemical opportunities to further improve existing electrochemical energy-storage technologies as they can be prepared from less-limited resources and potentially at low environmental footprint. Among the current explored research fields, the anion-ion cell configuration appears poorly investigated although quite promising to promote the fabrication of molecular (metal-free) rechargeable batteries. Herein, we report the synthesis and the electrochemical behavior of both Mg/Li salts of 2,5-(dianilino)terephthalate (MgDAnT and Li DAnT) and cross-linked polyviologen (c-PV ) that can reversibly uptake/extract anions at different working potentials, enabling the assembly of full anionic organic batteries.