Singlet fission preserves polarisation correlation of excitons.

Singlet fission (SF) holds the promise to circumvent the photovoltaic efficiency limit to reach a power-conversion efficiency above 34%. SF of TIPS-pentacene (TIPS-Pn) has been investigated but its mechanism is yet to be well elucidated. Recently, we developed a nanoparticle (NP) system, in which doping of TIPS-Pn in a host matrix yields a range of average intermolecular distances, , to study the dependence of SF in TIPS-Pn on .