Publications by authors named "Eleonora Conca"

Aluminium is the most common substrate in studies using impactors for the measurement of the number or the weight of size-segregated atmospheric particulate matter (PM), as its characteristics perfectly fit impactor requirements. However, its use is not recommended by manufacturers when one of the purposes of the study is the determination of the metal content in the sample. The aim of this work was to develop an efficient analytical procedure for the removal and acid digestion of PM samples collected on aluminium foils by a cascade impactor to perform the determination of metals.

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Trace heavy metals Cd, Pb, and Cu were determined (by square wave anodic stripping voltammetry) in aerosol samples collected at Dome C (the Italo-French Station Concordia), a remote site of the Central East Antarctic plateau, for which no data are available until now. During the Austral Summer 2005-2006, three PM10 high-volume impactors were installed in two locations nearby of Concordia station: the first one very close and downwind of the station (about 50 m north), the other two (very close to each other) in a 'distant' site, upwind of the station and close to the astrophysics tent (not used in that expedition) at ~800 m south of Station Concordia. For each sample, the availability of the mass of the aerosol collected (obtained by differential weighing carried out on site), in addition to the volume of the filtered air, allowed us to express results both in terms of metal mass fractions in the aerosol and in the usual way of metal atmospheric concentrations.

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A portable measurement and speciation procedure for inorganic mercury (Hg) and methylmercury (CHHg) was developed. A portable sample pretreatment was optimized to determine total mercury content. A new home-made sorbent (CYXAD, CHYPOS 101 modified Amberlite XAD), was prepared to separate Hg and CHHg.

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Article Synopsis
  • - The study optimized a two-step extraction process for analyzing trace elements in Arctic particulate matter (PM) using certified reference materials and compared five common extraction solutions and methods (stirring vs. ultrasounds).
  • - Results showed that ultrasound extraction led to lower recovery of elements, but diluted HNO3 was the most effective at extracting anthropogenic elements (like As, Cd, Pb, Zn) compared to crustal elements (like Al, Si, Ti).
  • - The improved procedure successfully minimized contamination and was applied to ten Arctic PM samples, revealing insights about the sources and similar chemical behavior of certain trace elements across different seasons.
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The inorganic component of hazelnuts was considered as a possible marker for geographical allocation and for the assessment of technological impact on their quality. The analyzed samples were Italian hazelnuts of the cultivar and Turkish hazelnuts of the cultivars , and . The hazelnuts were subjected to different drying procedures and different conservative methods.

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Major, minor and trace elements were determined in freshwater of lacustrine systems in Terra Nova Bay, along Victoria Land coast, Antarctica, as well as in algae and mosses. The samples were collected during some of the sampling campaigns between 2007 and 2011 (and the one of 2002) within the framework of the Italian National Program of Research in Antarctica (PNRA). Data were processed with chemometric techniques.

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