With a significant number of features (namely being multipurpose, inexpensive and durable), thermoplastic polymers, most often named plastics, are part of our daily routine, with an increasing production over the last decade. Among them, polyethylene terephthalate (PET), high-density polyethylene (HDPE) and polypropylene (PP) are distinguished as the five most commonly used plastics in various fields, mainly in the packaging industry. Even if it is difficult to imagine the world without plastics, the boosted plastic assembly comes with huge plastic waste, creating a number of challenges, as the most important threat for our environment, but also opportunities for recycling.
View Article and Find Full Text PDFThe glass transition temperature (Tg) is an important decision parameter when synthesizing polymeric compounds or when selecting their applicability domain. In this work, the glass transition temperature of more than 100 homopolymers with saturated backbones was predicted using a neuro-evolutive technique combining Artificial Neural Networks with a modified Bacterial Foraging Optimization Algorithm. In most cases, the selected polymers have a vinyl-type backbone substituted with various groups.
View Article and Find Full Text PDFThe operability of liquid crystal displays is strongly impacted by the orientation aspects of nematics, which in turn are affected by the alignment layer surface features. In this work, two polyimide (PI) structures are obtained based on a cycloaliphatic dianhydride and aromatic or aliphatic diamines with distinct flexibility. The attained PI films have high transmittance (T) for visible radiations, i.
View Article and Find Full Text PDFAromatic polyimides containing side azo-naphthalene groups have been investigated regarding their capacity of generating surface relief gratings (SRGs) under pulsed UV laser irradiation through phase masks, using different fluencies and pulse numbers. The process of the material photo-fluidization and the supramolecular re-organization of the surface were investigated using atomic force microscopy (AFM). At first, an AFM nanoscale topographical analysis of the induced SRGs was performed in terms of morphology and tridimensional amplitude, spatial, hybrid, and functional parameters.
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