A major problem that limits the use of biodiesel is maintaining the fuel at the specified standards for a longer period. Biodiesel oxidizes much more easily than diesel, and the final oxidation products change its physical and chemical properties and cause the formation of insoluble gums that can block fuel filters and the supply pipes. This instability of biodiesel is a major problem and has not yet been satisfactorily resolved.
View Article and Find Full Text PDFMaterials (Basel)
December 2022
Volatile organic compounds (VOCs) released in air represent a major potential for environmental pollution. Capture methods based on activated biochar have attracted attention because of their low cost and for the high removal capacity of the material due to its physical and chemical properties. In this paper, activated biochars were developed and their adsorption performance for VOC capture was evaluated.
View Article and Find Full Text PDFNanocomposites based on 13X zeolite (13XZ), calcium oxide (CaO) and metal zinc particles (Zn) were prepared. The resulting nanocomposites were characterized by different techniques. Then, a comparative study on catalytic and noncatalytic pyrolysis of biomass waste was performed to establish the influence of nanocomposites used as catalysts on the yields and characteristics of liquid and solid products.
View Article and Find Full Text PDFBioinorg Chem Appl
October 2022
This work was intended to develop catalysts based on 13X zeolite modified with transition metals for catalytic applications. In this regard, 13X zeolite was modified by loading of transition metals such as Fe, Co, Cu and various types of catalysts such as Fe-, Co-, Cu-, Fe-Co-, Fe-Cu-, and Co-Cu/13X zeolite were obtained. To prepare these catalysts, the wet impregnation method and metallic precursors were used.
View Article and Find Full Text PDFBy loading Cr and Zn on 13X zeolite, efficient nanocatalysts were prepared; they were characterized by different techniques and used for corn cobs pyrolysis to produce bio-oil. The corn cobs biomass (CCB) was washed with sulfuric acid 0.1 M, and the characteristics of the pretreated biomass (PTCCB) were analyzed.
View Article and Find Full Text PDFInt J Environ Res Public Health
December 2021
Volatile organic compounds (VOCs) comprise various organic chemicals which are released as gases from different liquids or solids. The nature and impact of the health effects are dependent on the VOCs concentrations and, also, on the exposure time. VOCs are present in different household, industrial or commercial and products, but their accumulation in air and water has primarily gained attention.
View Article and Find Full Text PDFAs an advanced oxidation process, the combination of sonolysis (US)/ozonolysis (O(3)) was investigated on the treatment of tannic acid (TA) and humic acid (HA). In this study, biodegradable chemicals were found by the molecular weight and GC-MS analysis method, and mineralization rate and synergetic effects were also studied. For the water samples prior to the treatment of US/O(3), ratios of molecular size higher than 5000 and 2000 Da for HA and TA, detected by the ultra filtration method, were 90.
View Article and Find Full Text PDFN-Propylsalicylaldimino-functionalized SBA-15 mesoporous silica was prepared, characterized and used as an adsorbent for heavy metal ions. The organic-inorganic hybrid material was obtained using successive grafting procedures of SBA-15 silica with 3-aminopropyl-triethoxysilane and salicylaldehyde, respectively. For comparison an amorphous silica gel was functionalized using the same procedure.
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