Effect of side-chain length on solute encapsulation by amphiphilic heterografted brush copolymers.

Anisotropic nanomaterials are non-spherical structures that possess unique shape-dependent physicochemical properties and functionalities. Inspired by the abundance of filamentous entities in nature, cylindrical nanostructures have gained significant attention due to their unique performance. Herein, we discuss the effect of side-chain length on the encapsulation properties of amphiphilic heterografted bottlebrushes.

Oxidative instability of boronic acid-installed polycarbonate nanoparticles.

Oxidative stress, caused by the overproduction of reactive oxygen species (ROS), is often observed in degenerative and/or metabolic diseases, tumors, and inflamed tissues. Boronic acids are emerging as a unique class of responsive biomaterials targeting ROS because of their reactivity toward H2O2. Herein, we examine the oxidative reactivity of nanoparticles from a boronic acid-installed polycarbonate.

Ionic Strength-Dependent Interactions and Dimensions of Adsorbed Zwitterionic Copolymers.

We report direct measurements of ionic strength-dependent interactions between different molecular weights of zwitterionic triblock copolymers adsorbed to hydrophobic colloids and surfaces. The zwitterionic copolymers investigated include phosphorylcholine [poly(2-methacryloyloxyethyl phosphorylcholine) (PMPC)] and sulfopropylbetaine [poly(3-( N-2-methacryloyloxyethyl- N, N-dimethyl)ammonatopropanesulfonate) (PMAPS)] end blocks separated by poly(propylene oxide) center blocks. The range of repulsion between adsorbed PMAPS copolymer layers increases with increasing NaCl from 0.