Reproducible Deep-UV SERRS on Aluminum Nanovoids.

Surface-enhanced Raman scattering (SERS) with deep-UV excitation is of particular interest because a large variety of biomolecules such as amino acids exhibit electronic transitions in the UV spectral range and resonant excitation dramatically increases the cross section of the associated vibrational modes. Despite its potential, UV-SERS is still little-explored. We present a novel straightforward scalable route to fabricate aluminum nanovoids for reproducible SERS in the deep-UV without the need of expensive lithographic techniques.

Non-linear plasmon response to protein binding at a nanostructured gold particle plasmon resonance surface.

Rapid adsorption kinetics have been observed for protein binding to a 800 nm aggregated nanoparticle, showing extreme sensitivity resulting from a non-linear particle plasmon response.

Light emission from whispering-gallery modes in microscopic spheres.

The emission of light from whispering-gallery modes excited in microscopic spheres is examined. An evanescent wave is produced by total internal reflection of an optical beam at a planar glass-air interface. This evanescent wave is used to excite whispering-gallery modes in single microscopic spheres placed behind the glass-air interface.

Light scattering by microscopic spheres behind a glass-air interface.

Scattering of light from single spheres placed behind a glass-air interface with light incident through the glass is examined. This scattering is investigated for both p- and s-polarized light incident at angles below the glass-air critical angle. The intensity of light scattered into the air half-space from each sphere is measured as a function of scattering angle, and this response is compared in situ with the background scatter produced by the planar substrate.