Observations of three "re-entrant" twisted structures in double-stranded DNA dispersion particles.

In this work we report on observations of new twisted (cholesteric-like) structures in liquid-crystalline dispersion particles with a hexagonal packing of double-stranded (ds) DNA molecules. Heating up to 80 °C of the DNA dispersion formed in a aqueous-salt solution with a high osmotic pressure (concentration) of poly(ethylene glycol) induces the formation of a new, optically active, spirally twisted structure of these molecules ("re-entrant" cholesteric structure (rest-A structure)). Cooling of this dispersion up to 22 °C is accompanied by the formation of an additional "re-entrant" cholesteric structure (rest-B).

Linear defects forming the ground state of polar free standing smectic-C* films.

In this paper we report on observations of unusual linear defects forming spontaneously in polar free-standing smectic-C* films near the temperatures of thinning transitions. At high temperature a periodic structure of defects becomes the ground state of the system. We found that the defects are characterized by continuous rotation of the molecular orientation with a change of the sense of the rotation across the defects.

The Dynamical Transition of Lipid Multilamellar Bilayers as a Matter of Cooperativity.

The present study is the application of a two-state model formerly developed by Bicout and Zaccai [ Bicout , D. J. and Zaccai , G.

Re-entrant cholesteric phase in DNA liquid-crystalline dispersion particles.

In this research, we observe and rationalize theoretically the transition from hexagonal to cholesteric packing of double-stranded (ds) DNA in dispersion particles. The samples were obtained by phase exclusion of linear ds DNA molecules from water-salt solutions of poly(ethylene glycol)-PEG-with concentrations ranging from 120 mg ml to 300 mg ml. In the range of PEG concentrations from 120 mg ml to 220 mg ml at room temperature, we find ds DNA molecule packing, typical of classical cholesterics.

Size independence of statistics for boundary collisions of random walks and its implications for spin-polarized gases.

A bounded random walk exhibits strong correlations between collisions with a boundary. For a one-dimensional walk, we obtain the full statistical distribution of the number of such collisions in a time t. In the large t limit, the fluctuations in the number of collisions are found to be size independent (independent of the distance between boundaries).

Observation of new states of liquid crystal 8CB under nonlinear shear conditions as observed via a novel and unique rheology/small-angle X-ray scattering combination.

New stable states of liquid crystal 8CB could be induced by nonlinear shear conditions and observed by a newly developed rheology/X-ray scattering setup using synchrotron X-ray radiation. Nonlinear oscillatory shear created a distorted sixth order orientational structure. Even when oscillatory shear is switched off, the induced structure remains stable and can be removed only by heating the system into the isotropic state.

Long range correlations in DNA: scaling properties and charge transfer efficiency.

We address the relation between long-range correlations and charge transfer efficiency in aperiodic artificial or genomic DNA sequences. Coherent charge transfer through the highest occupied molecular orbital states of the guanine nucleotide is studied using the transmission approach, and the focus is on how the sequence-dependent backscattering profile can be inferred from correlations between base pairs.