ACS Appl Mater Interfaces
February 2024
The piezoelectric response is a measure of the sensitivity of a material's polarization to stress or its strain to an applied field. Using X-ray Bragg coherent diffraction imaging, we observe that topological vortices are the source of a 5-fold enhancement of the piezoelectric response near the vortex core. The vortices form where several low-symmetry ferroelectric phases and phase boundaries coalesce.
View Article and Find Full Text PDFPyroelectricity describes the generation of electricity by temporal temperature change in polar materials. When free-standing pyroelectric materials approach the 2D crystalline limit, how pyroelectricity behaves remained largely unknown. Here, using three model pyroelectric materials whose bonding characters along the out-of-plane direction vary from van der Waals (InSe), quasi-van der Waals (CsBiNbO) to ionic/covalent (ZnO), we experimentally show the dimensionality effect on pyroelectricity and the relation between lattice dynamics and pyroelectricity.
View Article and Find Full Text PDFPhase retrieval is a numerical procedure concerned with the recovery of a complex-valued signal from measurements of its amplitude. We describe a generalization of this method for multi-wavelength data acquired in a coherent diffractive imaging experiment. It exploits the wavelength-dependent scaling of the support domain to recover separate reconstructions for each wavelength, providing new possibilities for coherent diffractive imaging experiments.
View Article and Find Full Text PDFLattice mismatch induced epitaxial strain has been widely used to tune functional properties in complex oxide heterostructures. Apart from the epitaxial strain, a large lattice mismatch also produces other effects including modulations in microstructure and stoichiometry. However, it is challenging to distinguish the impact of these effects from the strain contribution to thin film properties.
View Article and Find Full Text PDFMultiferroic heterostructures composed of thin layers of ferromagnetic and ferroelectric perovskites have attracted considerable attention in recent years. We apply ab initio computational methods based on density functional theory to study the magnetoelectric coupling at the (0 0 1) interface between [Formula: see text] (LSMO) and [Formula: see text] (PZT). Our study demonstrates that the ferroelectric polarization of PZT has a strong influence on the distribution of magnetization in LSMO.
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