The practical utilization of TiO as a semiconductor in dye-sensitized solar cells (DSSCs) has been set back by poor visible light absorption, high charge carrier recombination, and low electrical conductivity, which reduce the power conversion efficiency (PCE) and sustainability of the device. In this respect, perovskites with excellent properties, such as large surface area, good optical properties, high electrical conductivity, and superior electrochemical stability, have recently emerged as promising alternatives capable of overcoming the drawbacks of TiO. Herein, SrSmFeCoO (SSFC) perovskites were prepared via the ball milling method at various milling times of 0, 5, and 10 h, and the obtained samples were denoted by SSFC-0, SSCF-5, and SSCF-10, respectively.
View Article and Find Full Text PDFTechnological advancements are leading to an upsurge in demand for functional materials that satisfy several of humankind's needs. In addition to this, the current global drive is to develop materials with high efficacy in intended applications whilst practising green chemistry principles to ensure sustainability. Carbon-based materials, such as reduced graphene oxide (RGO), in particular, can possibly meet this criterion because they can be derived from waste biomass (a renewable material), possibly synthesised at low temperatures without the use of hazardous chemicals, and are biodegradable (owing to their organic nature), among other characteristics.
View Article and Find Full Text PDFDue to the finite nature, health and environmental hazards currently associated with the use of fossil energy resources, there is a global drive to hasten the development and deployment of renewable energy technologies. One such area encompasses perovskite solar cells (PSCs) that have shown photoconversion efficiencies (PCE) comparable to silicon-based photovoltaics, but their commercialisation has been set back by short-term stability and toxicity issues, among others. A tremendous potential to overcome these drawbacks is presented by the emerging applications of graphene derivative-based materials in PSCs as substitutes or components, composites with other functional materials, and enhancers of charge transport, blocking action, exciton dissociation, substrate coverage, sensitisation and stabilisation.
View Article and Find Full Text PDFSemiconductor materials have been recently employed in photovoltaic devices, particularly dye-sensitized solar cells (DSSCs), to solve numerous global issues, especially the current energy crisis emanating from the depletion and hazardous nature of conventional energy sources, such as fossil fuels and nuclear energy. However, progress for the past years has been mainly limited by poor electron injection and charge carrier recombination experienced by DSSCs at the photoanode. Thus, novel semiconductor materials such as bismuth oxide (BiO) have been investigated as an alternative photoanode material.
View Article and Find Full Text PDFIn recent years, carbon-based materials, particularly carbon nanotubes (CNTs), have gained intensive research attention in the fabrication of organic solar cells (OSCs) due to their outstanding physicochemical properties, low-cost, environmental friendliness and the natural abundance of carbon. In this regard, the low sheet resistance and high optical transmittance of CNTs enables their application as alternative anodes to the widely used indium tin oxide (ITO), which is toxic, expensive and scarce. Also, the synergy between the large specific surface area and high electrical conductivity of CNTs provides both large donor-acceptor interfaces and conductive interpenetrating networks for exciton dissociation and charge carrier transport.
View Article and Find Full Text PDFIn the past few years, dye-sensitized solar cells (DSSCs) have received considerable research attention, as potential alternatives to the commonly used, but expensive, silicon-based solar cells owing to the low-cost, facile fabrication procedures, less impact on the environment, capability of working even under low incoming light levels, and flexibility of DSSCs. However, the relatively low power conversion efficiencies (PCEs) and poor long-term operational stability of DSSCs still limit their large-scale and commercial applications. As a consequence, this has prompted tremendous research effort towards the realization of high performance and sustainable devices, through tailoring of the properties of the various DSSC components, approaches such as introducing novel materials and new synthesis techniques.
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