ACS Appl Mater Interfaces
June 2024
Perovskite quantum dots (PeQDs) have great application prospects in fields such as displays and solar cells due to their adjustable band gap, high absorption coefficient, high carrier mobility, and solution processability. However, the ionic crystal characteristic of PeQDs and their surface ligands have led to problems such as solvent sensitivity, poor crystal stability, and difficulty in adjusting the photoelectric properties, which are challenges in high-quality PeQDs. Here, to solve the problem of fluorescence degradation caused by phase change and loss of surface ligands during the purification process of CsPbI QDs, this work develops a purification strategy that finely regulates the polarity of the purification solvent, to obtain high-purity perovskite.
View Article and Find Full Text PDFThe high power-conversion efficiencies of hybrid perovskite solar cells encourage many researchers. However, their limited photostability represents a serious obstacle to the commercialization of this promising technology. Herein, we present an efficient method for improving the intrinsic photostability of a series of commonly used perovskite material formulations such as MAPbI, FAPbI, CsFAPbI, and CsMAFAPbI through modification with octenidine dihydroiodide (), which is a widely used antibacterial drug with two substituted pyridyl groups and two cationic centers in its molecular framework.
View Article and Find Full Text PDFThe results of numerical SRIM and SCAPS calculations for the ionization, displacement and heating of hybrid perovskites under the influence of protons (E = 0.15, 3.0 and 18 MeV) are presented and show that the lowest transfer energy is demonstrated by the MAPbI, FAPbBr and FAPbI compounds, which represent the greatest potential for use as solar cells in space devices.
View Article and Find Full Text PDFThe growing demand for cheap, safe, recyclable, and environmentally friendly batteries highlights the importance of the development of organic electrode materials. Here, we present a novel redox-active polymer comprising a polyaniline-type conjugated backbone and quinizarin and anthraquinone units. The synthesized polymer was explored as a cathode material for batteries, and it delivered promising performance characteristics in both lithium and potassium cells.
View Article and Find Full Text PDFQuasi-2D perovskites have recently flourished in the field of luminescence due to the quantum-confinement effect and the efficient energy transfer between different n phases resulting in exceptional optical properties. However, owing to the lower conductivity and poor charge injection, quasi-2D perovskite light-emitting diodes (PeLEDs) typically suffer from low brightness and high-efficiency roll-off at high current densities compared to 3D perovskite-based PeLEDs, which is undoubtedly one of the most critical issues in this field. In this work, quasi-2D PeLEDs with high brightness, reduced trap density, and low-efficiency roll-off are successfully demonstrated by introducing a thin layer of conductive phosphine oxide at the perovskite/electron transport layer interface.
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