The production of high-purity hydrogen from hydrogen storage materials with further direct use of generated hydrogen in fuel cells is still a relevant research field. For this purpose, nickel-molybdenum-plated copper catalysts (NiMo/Cu), comprising between 1 and 20 wt.% molybdenum, as catalytic materials for hydrogen generation, were prepared using a low-cost, straightforward electroless metal deposition method by using citrate plating baths containing Ni-Mo ions as a metal source and morpholine borane as a reducing agent.
View Article and Find Full Text PDFCarbonization of biomass residues followed by activation has great potential to become a safe process for the production of various carbon materials for various applications. Demand for commercial use of biomass-based carbon materials is growing rapidly in advanced technologies, including in the energy sector, as catalysts, batteries and capacitor electrodes. In this study, carbon materials were synthesized from hardwood using two carbonization methods, followed by activation with HPO, KOH and NaOH and doping with nitrogen.
View Article and Find Full Text PDFBackground: While healthcare-associated infections (HAIs) affect approximately 3.2-6.5% of hospitalised patients in the US and Europe, improving hand hygiene (HH) could reduce HAI rates.
View Article and Find Full Text PDFA Pt-coated Ni layer supported on a Ni foam catalyst (denoted PtNi/Ni) was investigated for the electro-oxidation of the formic acid (FAO) in acidic media. The prepared PtNi/Ni catalyst was studied as a function of the formic acid (FA) concentration at bare Pt and PtNi/Ni catalysts. The catalytic activity of the PtNi/Ni catalysts, studied on the basis of the ratio of the direct and indirect current peaks ()/() for the FAO reaction, showed values approximately 10 times higher compared to those on bare Pt, particularly at low FA concentrations, reflecting the superiority of the former catalysts for the electro-oxidation of FA to CO.
View Article and Find Full Text PDFNitrogen-doped activated carbons with controlled micro- and mesoporosity were obtained from wood and wastes via chemical processing using pre-treatment (pyrolysis at 500 °C and hydrothermally carbonization at 250 °C) and evaluated as oxygen reduction catalysts for further application in fuel cells. The elemental and chemical composition, structure and porosity, and types of nitrogen bonds of obtained catalyst materials were studied. The catalytic activity was evaluated in an alkaline medium using the rotating disk electrode method.
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