SIOMMS: Evolution and development.

Promotion of Machine and Mechanism Science (MMS) among young people worldwide is one of the missions of IFToMM. Conducting Student International Olympiads on MMS (SIOMMS) fully meets this mission and is considered as an essential tool for attracting talented youth to MMS as a science. The history of SIOMMS is approaching ten years.

Possibility of Protic Ionic Liquids Formation From Triethanolamine with Sulfonamides.

In this work, we have studied the products of interaction of triethanolamine with sulfonamides (4-chloro- and 4-nitrobenzenesulfonamide) and with bis(trifluoromethanesulfonyl)amide to show that it is possible to form protic ionic liquids. By using the hybrid functional B3LYP, we have made quantum-chemical calculations of the structure and energy of the formed compounds, and as part of the Natural bond orbital analysis, we have calculated the hydrogen bonds parameters. The structures of the obtained compounds have been confirmed by IR and NMR spectroscopy.

Differential mobility spectrometry with nanospray ion source as a compact detector for small organics and inorganics.

Electrospray ionization (ESI) is an important tool in chemical and biochemical survey and targeted analysis in many applications. For chemical detection and identification electrospray is usually used with mass spectrometry (MS). However, for screening and monitoring of chemicals of interest in light, low power field-deployable instrumentation, an alternative detection technology with chemical selectivity would be highly useful, especially since small, lightweight, chip-based gas and liquid chromatographic technologies are being developed.

Planar differential mobility spectrometer as a pre-filter for atmospheric pressure ionization mass spectrometry.

Ion filters based on planar DMS can be integrated with the inlet configuration of most mass spectrometers, and are able to enhance the quality of mass analysis and quantitative accuracy by reducing chemical noise, and by pre-separating ions of similar mass. This paper is the first in a series of three papers describing the optimization of DMS / MS instrumentation. In this paper the important physical parameters of a planar DMS-MS interface including analyzer geometry, analyzer coupling to a mass spectrometer, and transport gas flow control are considered.

Detection of Radiation-Exposure Biomarkers by Differential Mobility Prefiltered Mass Spectrometry (DMS-MS).

Technology to enable rapid screening for radiation exposure has been identified as an important need, and, as a part of a NIH / NIAD effort in this direction, metabolomic biomarkers for radiation exposure have been identified in a recent series of papers. To reduce the time necessary to detect and measure these biomarkers, differential mobility spectrometry - mass spectrometry (DMS-MS) systems have been developed and tested. Differential mobility ion filters preselect specific ions and also suppress chemical noise created in typical atmospheric-pressure ionization sources (ESI, MALDI, and others).