Understanding the Reducibility of CeO Surfaces by Proton-Electron Transfer from CpCr(CO)H.

CeO is a popular material in heterogeneous catalysis, molecular sensors, and electronics and owes many of its special properties to the redox activity of Ce, present as both Ce and Ce. However, the reduction of CeO with H (thought to occur through proton-electron transfer (PET) giving Ce and new OH bonds) is poorly understood due to the high reduction temperatures necessary and the ill-defined nature of the hydrogen atom sources typically used. We have previously shown that transition-metal hydrides with weak M-H bonds react with reducible metal oxides at room temperature by PET.

Determining the effects of AR/VR HMD design parameters (mass and inertia) on cervical spine joint torques.

This study aimed to determine gravitational and dynamic torques and muscle activity of the neck across a series of design parameters of head mounted displays (mass, center of mass, and counterweights) associated with virtual and augmented reality (VR/AR). Twenty young adult participants completed five movement types (Slow and Fast Flexion/Extension and Rotation, and Search) while wearing a custom-designed prototype headset that varied the three design parameters: display mass (0, 200, 500, and 750 g), distance of the display's center of mass in front of the eyes (approximately 1, 3, and 5 cm anteriorly), and counterweights of 0, 166, 332, and 500 g to balance the display mass of 500 g at 7 cm. Inverse dynamics of a link segment model of the head and headset provided estimates of the torques about the joint between the skull and the occiput-first cervical vertebrae (OC1) and joint between the C7 and T1 vertebrae (C7).

Ruthenium Complexes of Polyfluorocarbon Substituted Terpyridine and Mesoionic Carbene Ligands: An Interplay in CO Reduction.

In recent years terpyridines (tpy) and mesoionic carbenes (MIC) have been widely used in metal complexes. With the right combination with a metal center, both of these ligands are individually known to generate excellent catalysts for CO reduction. In this study, we combine the potentials of PFC (PFC=polyfluorocarbon) substituted tpy and MIC ligands within the same platform to obtain a new class of complexes, which we investigated with respect to their structural, electrochemical and UV/Vis/NIR spectroelectrochemical properties.