Self-Aggregation Control of Porphyrin for Enhanced Selective Covalent Organic Network Membranes.

Covalent organic networks (CONs) are considered ideal for precise molecular separation compared with traditional polymer membranes because their pores have a sharp molecular weight cut-off and a robust structure. However, challenges remain with regard to tuning pores as a prerequisite for facile membrane fabrication to a defect-free layer. Herein, a highly conjugated amino-porphyrin is used and exploited its tunable stacking behavior to fabricate porphyrin-based polyamide CONs with ordered structures through interfacial polymerization with acyl chlorides.

Development of an ion gel-based CO separation membrane composed of Pebax 1657 and a CO-philic ionic liquid.

A tough ion gel membrane containing a CO-philic ionic liquid, 1-ethyl-3-methylimidazolium tricyanomethanide ([Emim][C(CN)]), was developed, and its CO permeation properties were evaluated under humid conditions at elevated temperatures. Pebax 1657, which is a diblock copolymer composed of a polyamide block and a polyethylene oxide block, was used as the gel network of the ion gel membrane to prepare a tough ion gel with good ionic liquid-holding properties. The polyamide block formed a semicrystalline structure in [Emim][C(CN)] to toughen the ion gel membrane an energy dissipation mechanism.

Two-Dimensional Interlayer Space Induced Horizontal Transformation of Metal-Organic Framework Nanosheets for Highly Permeable Nanofiltration Membranes.

Laminar membranes comprising graphene oxide (GO) and metal-organic framework (MOF) nanosheets benefit from the regular in-plane pores of MOF nanosheets and thus can support rapid water transport. However, the restacking and agglomeration of MOF nanosheets during typical vacuum filtration disturb the stacking of GO sheets, thus deteriorating the membrane selectivity. Therefore, to fabricate highly permeable MOF nanosheets/reduced GO (rGO) membranes, a two-step method is applied.

Tough ion gels composed of coordinatively crosslinked polymer networks using ZIF-8 nanoparticles as multifunctional crosslinkers.

Constructing crosslinked polymer networks reversible interactions is a promising approach to recover the mechanical strength of damaged gels. In addition, by designing effective reversible crosslinks, the mechanical strength of the gel can be enhanced through energy dissipation based on the destruction of the crosslinks by an applied force. In this study, we introduced zeolitic imidazole framework-8 nanoparticles (ZIF-8 NPs), which acted as multifunctional crosslinkers, to provide multipoint coordination bonding with a poly(,-dimethylacrylamide)-based polymer network in a gel containing an ionic liquid.