Masked Reactivity of Hydrated Clusters of Monovalent Manganese Ions: Water Insertion versus Nitrous Oxide Activation-A Density Functional Theory Investigation.

Previous mass spectrometric (MS) studies demonstrated that singly charged hydration clusters of manganese ions [Mn(HO)] were, on one hand, highly reactive toward intracluster water insertion but, on the other hand, inert toward nitrous oxide activation. This contrast in reactivity has been rationalized by our present theoretical investigation for the interconversion between the pristine Mn(I) monovalent form as a monatomic ion in [Mn(HO)] and the oxidized Mn(III) trivalent form as a hydride-hydroxide in [HMnOH(HO)], as well as their reactivity toward nitrous oxide activation. Our theoretical interpretations are supported with quantum chemical calculations based on density functional theory (DFT), performed systematically for the cluster-size range of = 1 - 12.

The Diaphragmatic Initiated Ventilatory Assist (DIVA) trial: study protocol for a randomized controlled trial comparing rates of extubation failure in extremely premature infants undergoing extubation to non-invasive neurally adjusted ventilatory assist versus non-synchronized nasal intermittent positive pressure ventilation.

Background: Invasive mechanical ventilation contributes to bronchopulmonary dysplasia (BPD), the most common complication of prematurity and the leading respiratory cause of childhood morbidity. Non-invasive ventilation (NIV) may limit invasive ventilation exposure and can be either synchronized or non-synchronized (NS). Pooled data suggest synchronized forms may be superior.

Neisseria gonorrhoeae antimicrobial resistance patterns and associated risk factors in women of childbearing potential in northwestern Ethiopia.

Backgrounds: Neisseria gonorrhoeae causes gonorrhea and poses public health problems, including antimicrobial resistance. Current data on gonorrhea in prenatal participants in the study area are required. Thus, we aimed to identify gonorrhea prevalence, antimicrobial resistance, and risk factors among antenatal care clinic visitors in northwestern Ethiopia.

Soil erosion estimation and erosion risk area prioritization using GIS-based RUSLE model and identification of conservation strategies in Jejebe watershed, Southwestern Ethiopia.

Erosion of soil refers to the process of detaching and transporting topsoil from the land surface by natural forces such as water, wind, and other factors. As a result of this process, soil fertility is lost, water bodies' depth is reduced, water turbidity rises, and flood hazard problems, etc. Using a numerical model of erosion rates and erosion risks in the Jejebe watershed of the Baro Akobo basin in western Ethiopia, this study mapped erosion risks to prioritize conservation measures.

Assessment of Humoral Immune Response in Pre- and Post-Vaccinated Cattle Against Lumpy Skin Disease.

Introduction: Lumpy skin disease (LSD) is viral disease affecting cattle production and productivity in Ethiopia. As a prevention method, vaccinations have been used for a long period with a questionable output due to the existence of LSD outbreaks in vaccinated herds in different parts of Ethiopia.

Methods: A longitudinal study was performed from October 2019 to April 2020 with the objective of assessing the humoral immune response of cattle with a serum neutralization test (SNT) from different management systems in central Ethiopia.