Electronic and magnetic properties of porphyrin nanoribbons with chelated metals.

Advances in surface-assisted synthesis routes now allow for precise control in the preparation and modification of low-dimensional structures. The choice of molecular precursors plays a fundamental role in these processes since the structural details and properties of the resulting nanostructures directly depend on the molecular block used. From this perspective, units based on porphyrins have proven to be promising candidates for the construction of nanosystems with nontrivial geometry.

Electronic properties and carrier mobilities of nanocarbons formed by non-benzoidal building blocks.

Exotic 1D and 2D carbon nanostructures have been grown in the laboratory in the last few years by means of surface-assisted chemical routes. In these processes, the strategical choice of a molecular precursor plays a dominant role in the determination of the synthesized nanocarbon. Further variations of these techniques are able to produce non-benzoidal carbon quantum-dots (QDs).

Spin-polarized electronic properties of naphthylene-based carbon nanostructures.

The 2D naphthylene-β structure is a theoretically proposed sp nanocarbon allotrope based on the assembly of naphthalene-based molecular building blocks, which features metallic properties. We report that 2D naphthylene-β structures host a spin-polarized configuration which turns the system into a semiconductor. We analyze this electronic state in terms of the bipartition of the lattice.

Validation of the INCREMENT-SOT-CPE score in a large cohort of liver transplant recipients with carbapenem-resistant Enterobacterales infection.

Background: Management of infections due to carbapenemase-resistant Enterobacterales (CRE) in solid organ transplant (SOT) recipients remains a difficult challenge. The INCREMENT-SOT-CPE score has been specifically developed from SOT recipients to stratify mortality risk, but an external validation is lacking.

Methods: Multicenter retrospective cohort study of liver transplant (LT) recipients colonized with CRE infection who developed infection after transplant over 7-year period.

The electronic properties of non-conventional -graphyne nanoribbons.

Graphyne nanocarbons are composed of a mixture of sp and sp hybridized atoms in different ratios and distributions. In addition to pure hexagonal systems, non-conventional graphynic structures can also accommodate non-hexagonal rings, as proposed recently on the basis of previously studied haeckelites. Here we use computational simulations to investigate the electronic properties emerging from quantum confinement when such 2D systems are cast into different families of nanoribbons.