Ultrafast Optically Induced Perturbation of Oxygen Octahedral Rotations in Multiferroic BiFeO Thin Films.

The functional properties of complex oxides, including magnetism and ferroelectricity, are closely linked to subtle structural distortions. Ultrafast optical excitations provide the means to manipulate structural features and ultimately to affect the functional properties of complex oxides with picosecond-scale precision. We report that the lattice expansion of multiferroic BiFeO following above-bandgap optical excitation leads to distortion of the oxygen octahedral rotation (OOR) pattern.

Time-Resolved Structural Measurement of Thermal Resistance across a Buried Semiconductor Heterostructure Interface.

The precise control and understanding of heat flow in heterostructures is pivotal for advancements in thermoelectric energy conversion, thermal barrier coatings, and efficient heat management in electronic and optoelectronic devices. In this study, we employ high-angular-resolution time-resolved X-ray diffraction to structurally measure thermal resistance in a laser-excited AlGaAs/GaAs semiconductor heterostructure. Our methodology offers femtometer-scale spatial sensitivity and nanosecond time resolution, enabling us to directly observe heat transport across a buried interface.

Structural measurement of electron-phonon coupling and electronic thermal transport across a metal-semiconductor interface.

Scattering of energetic charge carriers and their coupling to lattice vibrations (phonons) in dielectric materials and semiconductors are crucial processes that determine the functional limits of optoelectronics, photovoltaics, and photocatalysts. The strength of these energy exchanges is often described by the electron-phonon coupling coefficient, which is difficult to measure due to the microscopic time- and length-scales involved. In the present study, we propose an alternate means to quantify the coupling parameter along with thermal boundary resistance and electron conductivity by performing a high angular-resolution time-resolved X-ray diffraction measurement of propagating lattice deformation following laser excitation of a nanoscale, polycrystalline metal film on a semiconductor substrate.

Subpicosecond Optical Stress Generation in Multiferroic BiFeO.

Optical excitation leads to ultrafast stress generation in the prototypical multiferroic BiFeO. The time scales of stress generation are set by the dynamics of the population of excited electronic states and the coupling of the electronic configuration to the structure. X-ray free-electron laser diffraction reveals high-wavevector subpicosecond-time scale stress generation following ultraviolet excitation of a BiFeO thin film.

Monitoring Particulate Matter with Wearable Sensors and the Influence on Student Environmental Attitudes.

The mobile monitoring of air pollution is a growing field, prospectively filling in spatial gaps while personalizing air-quality-based risk assessment. We developed wearable sensors to record particulate matter (PM), and through a community science approach, students of partnering Chicago high schools monitored PM concentrations during their commutes over a five- and thirteen-day period. Our main objective was to investigate how mobile monitoring influenced students' environmental attitudes and we did this by having the students explore the relationship between PM concentrations and urban vegetation.