Redox-Active Bisphosphonate-Based Viologens as Negolytes for Aqueous Organic Flow Batteries.

Viologen derivatives feature two reversible one-electron redox processes and have been extensively utilized in aqueous organic flow batteries (AOFBs). However, the early variant, methyl viologen (MVi), exhibits low stability in aqueous electrolytes, restricting its practical implementation in AOFB technology. In this context, leveraging the tunability of organic molecules, various substituents have been incorporated into the viologen core to achieve better stability, lower redox potential, and improved solubility.

Improving the Volumetric Capacity of Gallocyanine Flow Battery by Adding a Molecular Spectator.

Gallocyanine () was recently introduced as a promising aqueous-soluble electroactive molecule for preparing two-electron storage alkaline flow battery (FB) negolytes. The development of a cost-effective FB electrolyte is limited by the unexpectedly low solubility of . In this work, the compound 7-amino-4-hydroxy-2-naphthalenesulfonic acid was introduced as a molecular spectator to modulate the solubility of in KOH; this formulation allowed the preparation of a negolyte with a theoretical volumetric capacity of 32.

Enhanced electrochemical discharge of Li-ion batteries for safe recycling.

The recycling of spent lithium-ion batteries (LIBs) is crucial to sustainably manage resources and protect the environment as the use of portable electronics and electric vehicles (EVs) increases. However, the safe recycling of spent LIBs is challenging, as they often contain residual energy. Left untreated, this can trigger a thermal runaway and result in disasters during the recycling process.

Innovative multiple nanoemulsion (W/O/W) based on Chilean honeybee pollen improves their permeability, antioxidant and antibacterial activity.

Beehive derivatives, including honeybee pollen (HBP), have been extensively studied for their beneficial health properties and potential therapeutic use. Its high polyphenol content gives it excellent antioxidant and antibacterial properties. Today its use is limited due to poor organoleptic properties, low solubility, stability, and permeability under physiological conditions.

Polarization Calibration of a Microwave Polarimeter with Near-Infrared Up-Conversion for Optical Correlation and Detection.

This paper presents a polarization calibration method applied to a microwave polarimeter demonstrator based on a near-infrared (NIR) frequency up-conversion stage that allows both optical correlation and signal detection at a wavelength of 1550 nm. The instrument was designed to measure the polarization of cosmic microwave background (CMB) radiation from the sky, obtaining the Stokes parameters of the incoming signal simultaneously, in a frequency range from 10 to 20 GHz. A linearly polarized input signal with a variable polarization angle is used as excitation in the polarimeter calibration setup mounted in the laboratory.