Publications by authors named "E A Berdonosova"
Hydrogen adsorption ability is a key parameter characterizing advanced porous materials. Herein, the influence of platinum catalyst on the interaction of Cu-BTC with hydrogen is thoroughly investigated using volumetric measurements, calorimetric titration, XRD, and IR- and EPR spectroscopy. The first hydrogen adsorption by the Cu-BTC + Pt/C composite leads to an irreversible chemical reaction related to the formation of structural defects during synthesis.
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- The CoFeMnTiVZr alloy, created through rapid solidification, has a hexagonal Laves-phase structure and is analyzed for its electrochemical properties in hydrogen absorption/desorption.
- Cyclic voltammetry and electrochemical impedance spectroscopy reveal important details about the kinetics and efficiency of hydrogen storage within the alloy under varying voltage conditions.
- The alloy showcases a maximum hydrogen capacity of about 1.9 wt% at room temperature, with a consistent capacity of 1.7 wt% noted in gas-solid reactions, demonstrating its reliability for reversible hydrogen absorption.
Ultra-high-pressure hydrogen-storage performance (up to 1900 bar) was investigated for mesoporous chromium terephthalate MIL-101 and its inclusion compounds containing ionic clusters [Re(4)S(4)F(12)](4-) and [SiW(11)O(39)](7-) within the porous framework. The maximum specific hydrogen uptake values (total) for MIL-101 are 12.3 (at 81) and 7.
View Article and Find Full Text PDFSorption isotherms of methane in Zn(2)(bdc)(2)(dabco) are measured up to a pressure of 35 bar in the temperature range between 198-296 K. The methane sorption measurements at 296 K showed an uptake of 137 cm(3) cm(-3) at 35 bar. The enthalpy of methane adsorption for Zn(2)(bdc)(2)(dabco) estimated by the virial equation is 13.
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