Advances and challenges in biocathode microbial electrolysis cells for chlorinated organic compounds degradation from electroactive perspectives.

Microbial electrolysis cell (MEC) is a promising in-situ strategy for chlorinated organic compound (COC) pollution remediation due to its high efficiency, low energy input, and long-term potential. Reductive dechlorination as the most critical step in COC degradation which takes place primarily in the cathode chamber of MECs is a complex biochemical process driven by the behavior of electrons. However, no information is currently available on the internal mechanism of MEC in dechlorination from the perspective of the whole electron transfer procedure and its dependent electrode materials.