Publications by authors named "Dyanna Berroteran"
Org Biomol Chem
July 2003
Article Synopsis
- - The hydrolysis of five and six-membered cyclic phosphoramides in acidic conditions (pH 1.5 to 4) was studied using UV and 3'PNMR spectroscopy, revealing a specific reaction rate equation influenced by water attack on both protonated and unprotonated forms.
- - Contrary to expectations that five-membered rings would hydrolyze faster due to structural strain, the results showed they were only slightly quicker in one aspect but slower in another compared to six-membered rings, attributed to the increased stability of the latter's electron configuration.
- - The study found differing product ratios during hydrolysis; five-membered rings predominantly yielded products from endocyclic cleavage, while six-membered rings favored
