Mechanistic Innovations in Fluorescent Chemosensors for Detecting Toxic Ions: PET, ICT, ESIPT, FRET and AIE Approaches.

Fluorescent chemosensors have become vital tools for detecting toxic ions due to their exceptional sensitivity, selectivity, and rapid response times. These sensors function through various mechanisms, each providing unique advantages for specific applications. This review offers a comprehensive overview of the mechanistic innovations in fluorescent chemosensors, emphasizing five key approaches: Photoinduced Electron Transfer (PET), Fluorescence Resonance Energy Transfer (FRET), Intramolecular Charge Transfer (ICT), Aggregation-Induced Emission (AIE), and Excited-State Intramolecular Proton Transfer (ESIPT).

A review on polycyclic aromatic compounds based chemosensors for toxic ions detection - Present and future perspective.

This comprehensive review delves into the current landscape and future outlook of chemosensors constructed from polycyclic aromatic compounds (PACs) for the detection of toxic ions. PACs, known for their unique molecular properties, have emerged as key building blocks for the development of chemosensors due to their sensitivity, selectivity, and versatility. The review begins by providing an overview of the existing literature on PAC-based chemosensors, detailing their design principles, structural modifications, and mechanisms of ion recognition.

A Review on Small Molecule Based Fluorescence Chemosensors for Bioimaging Applications.

This review provides a thorough examination of small molecule-based fluorescence chemosensors tailored for bioimaging applications, showcasing their unique ability to visualize biological processes with exceptional sensitivity and selectivity. It explores recent advancements, methodologies, and applications in this domain, focusing on various designs rooted in anthracene, benzothiazole, naphthalene, quinoline, and Schiff base. Structural modifications and molecular engineering strategies are emphasized for enhancing sensor performance, including heightened sensitivity, selectivity, and biocompatibility.

A Review of Nanotechnology-Enabled Fluorescent Chemosensors for Environmental Toxic Ion Detection.

This review examines the utilization of nanotechnology-based chemosensors for identifying environmental toxic ions. Over recent decades, the creation of nanoscale materials for applications in chemical sensing, biomedical, and biological analyses has emerged as a promising avenue. Nanomaterials play a vital role in improving the sensitivity and selectivity of chemosensors, thereby making them effective tools for monitoring and evaluating environmental contamination.

A Review on Schiff Base Fluorescent Chemosensors for Cell Imaging Applications.

Fluorescent determinations of analytes have proven to be a powerful method due to their simplicity, low cost, detection limit, rapid photoluminescence response, and applicability to bioimaging. Fluorescence imaging as a powerful tool for monitoring biomolecules within the living systems. Schiff base has been extensively used as strongly absorbing and colorful chromophores in the design of chemosensors.

Detection of toxic fluoride ion via chromogenic and fluorogenic sensing. A comprehensive review of the year 2015-2019.

Fluoride ion (F) contamination can be accumulated along the water and the food chain and cause serious risk to public health. It is of the greatest importance that selects the suitable chromophores and fluorophores for the design and synthesis of outstanding selective, sensitive chromogenic and fluorogenic probes for detection of fluoride ion. In this review is mainly focused on the current progress of fluoride ion detection according to their receptors into several categories like anthracene, azo, benzothiazole, BODIPY, calixarene, coumarin, imidazole, diketopyrrolopyrrole, hydrazone, imidazole, naphthalene, naphthalimide, quantum dots, Schiff base and urea group sensing in the year 2015-2019.

Naked eye sensing of toxic metal ions in aqueous medium using thiophene-based ligands and its application in living cells.

Thiophene-based diimine (R1) and monoimine (R2) were synthesized in a single step, and their cation binding affinity was tested using colorimetric and UV-vis spectral studies. R1 selectively shows a colorimetric turn-on response for Pb(2+), Hg(2+) ions and colorimetric turn-off with Sn(2+) ions, and R2 shows visual response for Cu(2+) and Hg(2+) over other examined metal ions in aqueous medium. R1 forms 1:1 complex with Pb(2+), Hg(2+), and Sn(2+) and exhibits fluorescence quenching, whereas R2 shows 2:1 complex with Hg(2+), Cu(2+) and shows fluorescence enhancement.

Colorimetric chemosensor for multi-signaling detection of metal ions using pyrrole based Schiff bases.

Pyrrole based Schiff bases act as a highly sensitive probe for metal ions in aqueous medium. Both receptors R1 and R2 are sensitive towards Fe(3+), Cu(2+), Hg(2+) and Cr(3+) among the other metal ions. The sensing ability of the receptors are investigated via colorimetric, optical and emission spectroscopic studies.

Colorimetric and fluorescent sensing of transition metal ions in aqueous medium by salicylaldimine based chemosensor.

The cation sensing property of highly sensitive chromogenic receptor N, N'-bis (salicylidine)-o-phenylene diamine (receptor 1) was studied by visual observation, UV-vis spectroscopy and fluorescence spectroscopy. The proposed study has been targeted to sense the first transition series metal cations like Fe, Co, Ni and Cu. Binding affinity toward Cu is found to be of higher magnitude compared to the other three cations mentioned.