Persistent chlorinated organic contaminants in harbour porpoises from the North Sea, the Baltic Sea and Arctic waters.

Individual chlorinated biphenyls (CBs) and chlorinated pesticides (p,p'-DDT and metabolites, HCHs and HCB) were determined in blubber samples of 40 harbour porpoises (Phocoena phocoena) of different age and sex from the North Sea, the Baltic Sea and Greenland coastal waters. Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were analysed in a selected group of animals. sigma CB concentrations (medians) in North Sea immature specimens were similar (14.

CB pattern in the harbour porpoise: bioaccumulation, metabolism and evidence for cytochrome P450 IIB activity.

Metabolism of chlorobiphenyls (CBs) was studied in harbour porpoise by comparing patterns of CB-X/CB-153 ratios in blood, brain, liver and blubber with the patterns in herring, the main food source. The CBs were classified in five groups, based on the presence/absence of vicinal H-atoms (vic. Hs) in meta,para (m,p) and/or ortho,meta (o,m) positions and the number of ortho-Cl-atoms (ortho-Cls).

Toxic chlorobiphenyls in adipose tissue and whole blood of an occupationally/accidentally exposed man and the general population.

Individual polychlorinated biphenyl (CB) congeners in adipose and whole blood tissues of a capacitor manufacture worker (occupational/accidental exposure) and of the general population were determined. Nondestructive sample cleanup and multidimensional gas chromatography-electron capture detection (MDGC-ECD) techniques were applied. Special attention was given to the toxicologically relevant congeners CB-77, CB-126, CB-169, CB-105, CB-114, CB-118, CB-156, CB-167, and CB-189 (IUPAC).

Objectives, components and experiences in the development of The IOC Marine Pollution Monitoring System (MARPOLMON).

The Marine Pollution Monitoring System (MARPOLMON) constitutes a marine chemical component of the Global Environment Monitoring System (GEMS). The Programme covers all matters related to marine pollution research and associated monitoring activities required for the assessment of marine pollution. MARPOLMON constitutes the data-gathering activity, being directed to accurately determine levels of selected contaminants in several phases of the marine environment in various regions of the World Ocean.

Monitoring of cyclic organochlorines in the marine environment.

Cyclic organochlorines are highly hydrophobic chemicals which usually possess a high persistence to microbial breakdown. These behavioural aspects determine the suitability of each environmental compartment for monitoring purposes, which is discussed.It is concluded, that monitoring of (cyclic) organochlorines should only be executed for compounds about which solid information is available on their environmental behaviour in abiotic and biotic environmental compartments.

Kinetics of individual polychlorinated biphenyl (PCB) components in juvenile sole (Solea solea) in relation to their concentrations in food and to lipid metabolism.

PCBs were administered to juvenile soles (Solea solea) with food. Homogenates of gut, liver, brain, dark skin, muscle and gills were analysed for their contents of individual PCB components. The relative contributions of individual components to total PCB were virtually identical in the various organs sampled at the same day in a 275-day period.