In this study, a self-encapsulated Sb-C nanocomposite as an anode material for sodium-ion batteries (SIBs) was successfully synthesised using an SbCl-citrate complex precursor, followed by a drying and calcination process under an inert N atmosphere. When the molar ratio of SbCl to citric acid was varied from 1 : 1 to 1 : 4, the Sb-C nanocomposite with a molar ratio of 1 : 3 (Sb-C3) exhibited the highest specific surface area (265.97 m g) and pore volume (0.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2017
Here, we propose a simple method for direct synthesis of a Si@SiC composite derived from a SiO@C precursor via a Mg thermal reduction method as an anode material for Li-ion batteries. Owing to the extremely high exothermic reaction between SiO and Mg, along with the presence of carbon, SiC can be spontaneously produced with the formation of Si. The synthesized Si@SiC was composed of well-mixed SiC and Si nanocrystallites.
View Article and Find Full Text PDFA composite gel polymer electrolyte (CGPE) based on poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) polymer that includes Al-doped Li0.33La0.56TiO3 (A-LLTO) particles covered with a modified SiO2 (m-SiO2) layer was fabricated through a simple solution-casting method followed by activation in a liquid electrolyte.
View Article and Find Full Text PDFAn effective integrated design with a free standing and carbon-free architecture of spinel MnCo2O4 oxide prepared using facile and cost effective hydrothermal method as the oxygen electrode for the Li-O2 battery, is introduced to avoid the parasitic reactions of carbon and binder with discharge products and reaction intermediates, respectively. The highly porous structure of the electrode allows the electrolyte and oxygen to diffuse effectively into the catalytically active sites and hence improve the cell performance. The amorphous Li2O2 will then precipitate and decompose on the surface of free-standing catalyst nanorods.
View Article and Find Full Text PDFIn this study, a novel method has been proposed for synthesizing amorphous GeO2/C composites. The amorphous GeO2/C composite without carbon black as an electrode for Li-ion batteries exhibited a high specific capacity of 914 mA h g(-1) at the rate of C/2 and enhanced rate capability. The amorphous GeO2/C electrode exhibited excellent electrochemical stability with a 95.
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