Various α-Fe O hollow structures, such as wormlike shapes, ellipsoids, and quasicubes, were synthesized successfully by a halide-ion-assisted solvothermal method. The self-assembly assisted by selective absorption of halide ions and Ostwald ripening speeded up by acidic etching commonly determine the final unique structures. The electrochemical performance of the α-Fe O with different structures in reversible lithium-ion storage was investigated, and showed that the hollow Fe O quasicubes exhibit the best cycling performance with a charge capacity of 401.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2014
In this study, three-dimensional cobalt oxide microstructures were developed. Cobalt oxide microdumbbells and microspheres, assembled by nanowires and primary particles, were successfully synthesized by a multistep hydrothermal method. Of all of the structures, the cobalt oxide microdumbbell electrode possesses the largest surface area of 70.
View Article and Find Full Text PDFACS Appl Mater Interfaces
June 2014
In this study, we report a facile and simple approach to synthesize a composite of mesoporous NiO nanowires and graphene nanosheets for supercapacitor applications. A Ni precursor was prepared by a one-pot sol-gel method in a water/ethylene glycol mixture containing a graphene oxide. Heat treatment in air was carried out to thermally reduce the graphene oxide to graphene and to convert the Ni precursor to NiO.
View Article and Find Full Text PDF