Spectrometer-Less Remote Sensing Image Classification Based on Gate-Tunable van der Waals Heterostructures.

Remote sensing technology, which conventionally employs spectrometers to capture hyperspectral images, allowing for the classification and unmixing based on the reflectance spectrum, has been extensively applied in diverse fields, including environmental monitoring, land resource management, and agriculture. However, miniaturization of remote sensing systems remains a challenge due to the complicated and dispersive optical components of spectrometers. Here, m-phase GaTeSe with wide-spectral photoresponses (250-1064 nm) and stack it with WSe are utilizes to construct a two-dimensional van der Waals heterojunction (2D-vdWH), enabling the design of a gate-tunable wide-spectral photodetector.

Fog scavenging of particulate matters in air pollution events: Observation and simulation in the Yangtze River Delta, China.

Stable atmospheric boundary layer is conducive to the accumulation of atmospheric pollution and the occurrence of fog, and fog has a removal effect on air pollution. In this study, we use the observation and WRF-Chem (Weather Research and Forecasting Model with Chemistry) simulation to analyze the factors affecting the removal efficiency in a continuous fog and haze episode from November 26 to 28, 2018 in Jiangsu Province, such as fog thickness and duration. The results show that the WRF-Chem simulation well reproduces the boundary layer characteristics in the stages of fog formation, development and dissipation.

The interaction between black carbon and planetary boundary layer in the Yangtze River Delta from 2015 to 2020: Why O didn't decline so significantly as PM.

Since the Air Pollution Prevention and Control Action Plan (air clean plan) issued in 2013, air quality has been in continuous improvement. The second stage of air clean plan since 2018 was focused on O controlling, but it still didn't decline so significantly as PM. This study conducted a long-term observation on black carbon (BC) and utilized the observational data of other air pollutants (PM, PM, NO, SO, CO and O), the meteorological elements and the vertical sounding data of PBL in Nanjing.

Estimation of radiative forcing and heating rate based on vertical observation of black carbon in Nanjing, China.

Owing to a lack of vertical observations, the impacts of black carbon (BC) on radiative forcing (RF) have typically been analyzed using ground observations and assumed profiles. In this study, a UAV platform was used to measure high-resolution in-situ vertical profiles of BC, fine particles (PM), and relevant meteorological parameters in the boundary layer (BL). Further, a series of calculations using actual vertical profiles of BC were conducted to determine its impact on RF and heating rate (HR).

An efficient method for the synthesis of 2-pyridones C-H bond functionalization.

A simple and practical method to access N-substituted 2-pyridones via a formal [3+3] annulation of enaminones with acrylates based on RhIII-catalyzed C-H functionalization was developed. Control and deuterated experiments led to a plausible mechanism involving C-H bond cross-coupling and aminolysis cyclization. This strategy provides a short synthesis of structural motifs of N-substituted 2-pyridones.

Decarboxylative C-H Alkylation of Heteroarene -Oxides by Visible Light/Copper Catalysis.

This paper reports a highly site-selective alkylation of heteroarene -oxides using hypervalent iodine(III) carboxylates to serve as an alkylating agent in the presence of a cheap copper catalyst under visible light conditions. This mild method proceeds at room temperature in an air atmosphere and can withstand various heteroarene -oxides as well as various primary, secondary, and tertiary alkyl carboxylic acids. It also provides a practical method for enabling the rapid conversion of commercially available raw materials into medically relevant "drug-like" molecules.

Atmospheric Ammonia in Beijing during the COVID-19 Outbreak: Concentrations, Sources, and Implications.

This study investigates the concentrations and δN values of NH in Beijing during and after the 2020 COVID-19 lockdown. Higher NH concentrations and lower δN-NH were observed at most sites in 2020 compared to 2017. Except for a site inside a tunnel, NH concentrations did not increase significantly after the lockdown had ended compared to those during the lockdown, while δN-NH increased by 2.

Meteorological Variables and Synoptic Patterns Associated with Air Pollutions in Eastern China during 2013-2018.

Steady meteorological conditions are important external factors affecting air pollution. In order to analyze how adverse meteorological variables affect air pollution, surface synoptic situation patterns and meteorological conditions during heavy pollution episodes are discussed. The results showed that there were 78 RPHPDs (regional PM pollution days) in Jiangsu, with a decreasing trend year by year.

FCG-ASpredictor: An Approach for the Prediction of Average Speed of Road Segments with Floating Car GPS Data.

The average speed (AS) of a road segment is an important factor for predicting traffic congestion, because the accuracy of AS can directly affect the implementation of traffic management. The traffic environment, spatiotemporal information, and the dynamic interaction between these two factors impact the predictive accuracy of AS in the existing literature, and floating car data comprehensively reflect the operation of urban road vehicles. In this paper, we proposed a novel road segment AS predictive model, which is based on floating car data.

Traffic Speed Prediction: An Attention-Based Method.

Short-term traffic speed prediction has become one of the most important parts of intelligent transportation systems (ITSs). In recent years, deep learning methods have demonstrated their superiority both in accuracy and efficiency. However, most of them only consider the temporal information, overlooking the spatial or some environmental factors, especially the different correlations between the target road and the surrounding roads.

α-Amino Acetal: A Synthetic Intermediate for the Construction of Aza-Polycycles.

One-step construction of aza-polycyclic skeletons was realized through double cyclization of the oxocarbenium and carbocation intermediates generated from α-amino acetals, which were designed and synthesized by employing our α-amination protocol of aldehydes. A simple process, a broad substrate range, commercialized materials, and extensive applications demonstrated the generality and effectiveness of this method.

Chemical compositions of fog and precipitation at Sejila Mountain in the southeast Tibetan Plateau, China.

Chemical compositions of fog and rain water were measured between July 2017 and September 2018 at Sejila Mountain, southeast Tibet, where fog events frequently occurred in original fir forests at altitude 3950 m. Fog water samples were collected using a Caltech Active Strand Cloud Collector (CASCC), and rain samples were collected using a precipitation gauge. Differences were observed between fog water and rain composition for most analyzed ions.

Eps15 homology domain 1 promotes the evolution of papillary thyroid cancer by regulating endocytotic recycling of epidermal growth factor receptor.

Papillary thyroid cancer (PTC) is the most common type of thyroid malignancy, and it is often observed to overexpress epidermal growth factor receptor (EGFR). Previous research has indicated that EH domain-containing 1 (EHD1) is associated with EGFR-mediated endocytotic recycling in multiple tumor types. The objective of the present study was to determine the protein expression levels and clinical significance of EHD1, EGFR, caveolin-1 (CAV-1) and RAB11 family interacting protein 3 (RAB11FIP3) in PTC.

HE4 level in ascites may assess the ovarian cancer chemotherapeutic effect.

Background: The clinical treatment of ovarian cancer with ascites is problematic. The main reasons for treatment failure are the susceptibility to intraperitoneal metastasis and chemotherapeutic drug resistance. The purpose and significance of this study is to evaluate which marker might evaluate treatment efficacy and improve the cure rate.

Relationship between infiltrating lymphocytes in cancerous ascites and dysfunction of Cajal mesenchymal cells in the small intestine.

Malignant ascites changes the microenvironment of the peritoneal cavity and damages abdominal functional host cells such as interstitial cells of Cajal (ICC), causing gastrointestinal dysfunction and poor prognosis. Besides tumor cells, malignant ascites contains large numbers of lymphocytes and macrophagocytes. These inflammatory cells act as a 'double arrow' and it is not clear whether they cause injury to ICCs.

Increased autophagy in EOC re-ascites cells can inhibit cell death and promote drug resistance.

As the major and preferred treatment for ovarian cancer ascites, chemotherapy can reduce or inhibit recurrent ascites (hereafter re-ascites); however, some patients still experience re-ascites. Therefore, this study investigated cases in which epithelial ovarian cancer (EOC) patients experienced re-ascites. In re-ascites cases, CA125, MDR1, LC-3, and Beclin-1 were highly expressed.

The impact of inflammatory cells in malignant ascites on small intestinal ICCs' morphology and function.

Malignant ascites is one of the common complication at the late stage of abdominal cancers, which may deteriorate the environment of abdominal cavity and lead to potential damage of functional cells. Interstitial cells of Cajal (ICCs) are mesoderm-derived mesenchymal cells that function normal gastrointestinal motility. The pathological changes of ICCs or the reduced number may lead to the motility disorders of gastrointestinal tract.

[Trends of urban haze in Jiangsu Province China over the past 33 years].

Based on the surface meteorological data of Jiangsu Province during 1980-2012, climatic characteristics and trends of the weather phenomenon of haze were analyzed. The result indicates that during 1980-2012, the haze day increased, and the severe and moderate haze days significantly increased. In the northern and coastal cities, haze days had a significant increase.

Association of insulin gene variable number of tandem repeats regulatory polymorphism with polycystic ovary syndrome.

The present meta-analysis aimed to investigate the association between insulin gene variable number of tandem repeats (INS VNTR) and polycystic ovary syndrome (PCOS). Systematic searches of electronic databases, reference lists of included articles, and the abstracts presented at related scientific societies meetings were performed. Statistical analyses were conducted using software Stata 11.