Pattern-directed to isotropic dewetting transition in polymer films on micropatterned surfaces with differential surface energy contrast.

Surface chemical patterns can both cause and direct dewetting in overlying thin polymer films. In this paper we focus on a key factor in this phenomenon, the magnitude of the surface energy difference between surface pattern domains (Δ). To probe the influence of Δ on film dewetting, we utilize novel combinatorial test patterns exhibiting a gradient in Δ.

Gradient chemical micro patterns: a reference substrate for surface nanometrology.

We present fabrication routes for a new type of surface specimen that exhibits a micro pattern with a gradient in chemical contrast between the pattern domains. Design elements in the specimen allow chemical contrast in the micro pattern to be related to well-established surface characterization data, such as contact angle measurements. These gradient specimens represent a reference tool for calibrating image contrast in chemically sensitive scanning probe microscopy techniques and a platform for the high-throughput analysis of polymer thin film behavior.

Ultrathin binary grafted polymer layers with switchable morphology.

Polymer surface layers comprised of mixed chains grafted to a functionalized silicon surface with a total layer thickness of only 1-3 nm are shown to exhibit reversible switching of their structure. Carboxylic acid-terminated polystyrene (PS) and poly (butyl acrylate) (PBA) were chemically attached to a silicon surface that was modified with an epoxysilane self-assembled monolayer by a "grafting to" routine. While one-step grafting resulted in large, submicron microstructures, a refined, two-step sequential grafting procedure allowed for extremely small spatial dimensions of PS and PBA domains.

Y-shaped amphiphilic brushes with switchable micellar surface structures.

We observed novel nanoscale surface structures of segregated pinned micelles and craterlike micelles formed by grafted Y-shaped molecules and their reversible reorganization in selective solvents. The Y-shaped molecules have two incompatible polymer chains (polystyrene and poly(tert-butyl acrylate)) attached to a functional stemlike segment capable of covalent grafting to a functionalized silicon surface. Postgrafting hydrolysis of poly(tert-butyl acrylate) arms imparts amphiphilicity to the brush.