How positive emotions affect entrepreneurial intention of college students: A moderated mediation model.

Entrepreneurial intention (EI) is a crucial requirement for encouraging significant entrepreneurial activity, which is essential for economic growth and social stability. Cultivating college students' EI is a critical element of higher education. Based on the theory of planned behavior (TPB), this study constructs a moderated mediation model, aiming to explore the intricate processes and conditioning elements that influence the EI of college students and investigate the mediating role of future time perspective (FTP) between positive emotion (PE) and entrepreneurial intention (EI) among Chinese college students, as well as the moderating role of gender.

Identification of cryptic breakpoints through single-tube long fragment read whole genome sequencing based on preimplantation genetic testing.

This study utilized single-tube long fragment read whole genome sequencing (stLFR WGS) to identify cryptic chromosomally balanced translocations in preimplantation genetic testing (PGT), aiming to improve outcomes for couples experiencing recurrent pregnancy loss (RPL). G-banded karyotyping initially revealed normal results for Family 1 and a reciprocal translocation for Family 2. However, PGT's low-coverage WGS uncovered recurrent copy number variations (CNVs) that contradicted the initial findings.

Exploring Photochemical Conversion of NO to HONO on N-Heterocycles: Unique Variation Trend of Gases, Kinetics, and Mechanism.

The photochemical conversion of NO to nitrous acid (HONO) on N-heterocycles and the corresponding benzene compounds was investigated through a flow tube reactor coupled with the methods of spectroscopy, mass spectrum, and theoretical calculation. The average uptake coefficient of NO on organics during 1 h (γ) varied in the range of (1.1-8.

Transcriptomic and biochemical insights into key gene networks driving bulbil development of Pinellia ternata (Thunb.) Breit.

In this study, we explored the developmental characteristics of Pinellia ternate bulbils as well as the key gene networks driving the development of bulbils. Based on physiological and biochemical reactions as well as transcriptome technology, this study determined the content of endogenous metabolites and related enzyme activities during the five growth stages of the bulbils, obtained the transcriptome information of all samples. The results showed that the contents of sucrose and starch increased significantly in the ZY_2 and ZY_4 stages, and the changes in the activities of SPS, SuSy, and SS were basically consistent with the changing characteristics of sucrose and starch content.

Disorder-induced enhancement of lithium-ion transport in solid-state electrolytes.

Enhancing the ion conduction in solid electrolytes is critically important for the development of high-performance all-solid-state lithium-ion batteries (LIBs). Lithium thiophosphates are among the most promising solid electrolytes, as they exhibit superionic conductivity at room temperature. However, the lack of comprehensive understanding of their ion conduction mechanism, especially the effect of structural disorder on ionic conductivity, is a long-standing problem that limits further innovations in all-solid-state LIBs.

An iliac arteriovenous fistula associated with leg swelling 2 years after the removal of a hemodialysis catheter: A case report.

Rationale: Temporary central venous catheters are commonly used for patients who require emergency hemodialysis. In rare instances, this procedure can result in a very serious complication known as arteriovenous fistula (AVF). Although some cases of femoral arteriovenous fistula have been reported previously in the literature; however, the incidence of iliac AVF precipitated by a hemodialysis catheter is exceedingly uncommon.

Nitrogen-doped nanocarbon as a metal-free catalyst for CO hydroboration.

Designing heterogeneous metal-free catalysts for highly efficient transformation of CO into valuable products is a dream goal and a long-standing challenge in thermal catalysis. Herein, N-doped nanocarbon catalysts, NOLCx, are synthesized and present an attractive ability to catalyse CO hydroboration. N doping on the NOLCx surface mainly exists in the form of pyridinic N, pyrrolic N and graphitic N, where pyridinic N and pyrrolic N are the possible catalytic active sites.

Intelligent Optimization and Impact Analysis of Energy Efficiency and Carbon Reduction in the High-Temperature Sintered Ore Production Process.

The coordinated optimization of energy conservation, efficiency improvement, and pollution reduction in the sintering production process is vital for the efficient and sustainable development of the sintering department. However, previous studies have shown shortcomings in the multi-objective collaborative optimization of sintering systems and the quantification of pollutant impacts. To address these, this paper proposes a multi-objective optimization method integrated with the NSGA-III algorithm and establishes an integrated system optimization model for sintered ore production and high-temperature waste heat recovery.

Revision Surgery of Microvascular Decompression for Hemifacial Spasm: 2-Dimensional Operative Video.

Although microvascular decompression is highly effective for treating hemifacial spasm, cases of ineffectiveness and recurrence can still occur. Ineffectiveness is primarily due to missed neurovascular compression (NVC), whereas recurrence is most often caused by adhesion of Teflon pledgets (Chestmedical Co., Ltd.

Opportunities and Challenges of Multi-Ion, Dual-Ion and Single-Ion Intercalation in Phosphate-Based Polyanionic Cathodes for Zinc-Ion Batteries.

With the continuous development of science and technology, battery storage systems for clean energy have become crucial for global economic transformation. Among various rechargeable batteries, lithium-ion batteries are widely used, but face issues like limited resources, high costs, and safety concerns. In contrast, zinc-ion batteries, as a complement to lithium-ion batteries, are drawing increasing attention.

Bidirectional Two-Sample Mendelian Randomization Analysis Reveals Causal Associations Between Modifiable Risk Factors and Fibromyalgia.

Introduction: This study aims to investigate the potential causal effects of modifiable risk factors on Fibromyalgia (FM).

Methods: Genetic variants associated with 34 exposure factors were obtained from Genome-wide association studies (GWAS). Summary statistics for FM were acquired from the FinnGen consortium.

Darolutamide-mediated phospholipid remodeling induces ferroptosis through the SREBP1-FASN axis in prostate cancer.

Darolutamide, an androgen receptor inhibitor, has been approved by the Food and Drug Administration (FDA) for the treatment of prostate cancer (PCa), especially for patients with androgen receptor mutations. Owing to the unique lipidomic profile of PCa and the effect of darolutamide, the relationship between darolutamide and ferroptosis remains unclear. The present study showed that darolutamide significantly induces ferroptosis in AR PCa cells.

Exploring the J-shaped relationship between HALP score and mortality in cancer patients: A NHANES 1999-2018 cohort study.

Background: The recent hemoglobin, albumin, lymphocyte, and platelet (HALP) scores, combined with various clinically available indicators, can comprehensively evaluate the nutritional and immune status of patients. Some observational studies have found a positive correlation between HALP score and cancer prognosis, but the clinical application of HALP score has raised concerns due to the presence of confounding factors. The aim of this study is to explore the relationship between HALP score and long-term mortality in cancer patients.

Cross-View Representation Learning-Based Deep Multiview Clustering With Adaptive Graph Constraint.

Deep multiview clustering provides an efficient way to analyze the data consisting of multiple modalities and features. Recently, the autoencoder (AE)-based deep multiview clustering algorithms have attracted intensive attention by virtue of their rewarding capabilities of extracting inherent features. Nevertheless, most existing methods are still confronted by several problems.

Co-adsorbed self-assembled monolayer enables high-performance perovskite and organic solar cells.

Self-assembled monolayers (SAMs) have become pivotal in achieving high-performance perovskite solar cells (PSCs) and organic solar cells (OSCs) by significantly minimizing interfacial energy losses. In this study, we propose a co-adsorb (CA) strategy employing a novel small molecule, 2-chloro-5-(trifluoromethyl)isonicotinic acid (PyCA-3F), introducing at the buried interface between 2PACz and the perovskite/organic layers. This approach effectively diminishes 2PACz's aggregation, enhancing surface smoothness and increasing work function for the modified SAM layer, thereby providing a flattened buried interface with a favorable heterointerface for perovskite.

Red/near-infrared (NIR) difluoroboron β-diketonate derivatives with reversible mechanochromism for cellular imaging.

Near-infrared (NIR) fluorophores have promoted the development of materials for bioimaging, but traditional NIR dyes usually suffer from aggregation-caused quenching (ACQ), impeding their applications. Herein, we propose two difluoroboron β-diketonate complexes TBO and TBS, consisting a donor-acceptor (D-A) structure with triphenylamine (TPA) moiety as an electron donors and difluoroboron as well as furan or thiophene building block as an electron acceptor. The theoretical calculation and optical data shows that both of them have intramolecular charge transfer (ICT) characteristics.

Important yet Overlooked HONO Source from Aqueous-phase Photochemical Oxidation of Nitrophenols.

Nitrites (NO/HONO), as the primary source of hydroxyl radicals (OH) in the atmosphere, play a key role in atmospheric chemistry. However, the current understanding of the source of NO/HONO is insufficient and therefore hinders the accurate quantification of atmospheric oxidation capacity. Herein, we highlighted an overlooked HONO source by the reaction between nitrophenols (NPs) and OH in the aqueous phase and provided kinetic data to better evaluate the contribution of this process to atmospheric HONO.

The evolutionary game of establishing a remote consultation system based on the downward allocation of medical resources in a medical alliance.

As a crucial component of hierarchical diagnosis and treatment systems, medical alliances in China are responsible for promoting the downward allocation of high-quality medical resources. Remote consultation, as an essential means to achieve this goal, is of practical importance in the realization of resource sharing between hospitals within medical alliances in China. The existing research on the construction of remote consultations within medical alliances has achieved fruitful results in both theory and practice.

Preparation of catalyst for CO hydrogenation reaction based on the idea of element sharing and preliminary exploration of catalytic mechanism.

Under the background of the continuous rise of CO annual emissions, the development of CO capture and utilization technology is urgent. This study focuses on improving the catalytic capacity of the catalyst for CO hydrogenation, improving the efficiency of CO conversion to methanol, and converting H into chemical substances to avoid the danger of H storage. Based on the concept of element sharing, the ASMZ (Aluminum Shares Metal Zeolite catalysts) series catalyst was prepared by combining the CuO-ZnO-AlO catalyst with the ZSM-5 zeolite using the amphoteric metal properties of the Al element.

[Analysis of Risk Factors for Recurrent Pregnancy Loss in Patients Undergoing Fertilization-Embryo Transfer].

Objective: Recurrent pregnancy loss (RPL) presents a formidable challenge for individuals undergoing fertilization-embryo transfer (IVF-ET), forming both a clinical dilemma and a focal point for scientific inquiry. This study endeavors to investigate the intricate interplay between clinical features, such as age, body mass index (BMI), and waist-to-hip ratio (WHR), and routine laboratory parameters, including sex hormones, blood composition, liver and thyroid functions, thyroid antibodies, and coagulation indicators, in RPL patients undergoing IVF-ET. By meticulously analyzing these variables, we aim to uncover the latent risk factors predisposing individuals to RPL.

TRIM28 Regulates Proliferation of Gastric Cancer Cells Partly Through SRF/IDO1 Axis.

Gastric cancer (GC) is one of the most common malignancies worldwide, with high incidence and mortality rate. Tripartite motif-containing 28 (TRIM28) is an important molecule that affects the occurrence and development of tumors, but its function in GC has not been elucidated clearly. The purpose of this study is to explore the molecular mechanism by which TRIM28 affect the GC.

Reactive oxygen species play key roles in the nitrite formation by the inorganic nitrate photolysis in the presence of urban water-soluble organic carbon.

Inorganic nitrates were considered to be a potential source of atmospheric NO/HONO during the daytime. To better evaluate the contribution of nitrate photochemistry on NO/HONO formation, the photolysis of nitrates in the real atmospheric environment needs to be further explored. Here, the NO generation by the photolysis of inorganic nitrates in the presence of total water-soluble organic carbon (WSOC) was quantified.

Development and Validation of a Prognostic Model based on 11 E3-related Genes for Colon Cancer Patients.

Background: Colon cancer is a common tumor in the gastrointestinal tract with a poor prognosis. According to research reports, ubiquitin-dependent modification systems have been found to play a crucial role in the development and advancement of different types of malignant tumors, including colon cancer. However, further investigation is required to fully understand the mechanism of ubiquitination in colon cancer.