A flow injection method has been developed for determination of silver. The method is based on a reduction reaction with sodium borohydride which leads to the formation of a colloidal species which is monitored at a wavelength of 390 nm. The reaction variables flow rate, sodium borohydride concentration and pH, which affect sensitivity, were investigated and their effects were established using a two-levels, three-factor experimental design.
View Article and Find Full Text PDFA photothermal experiment with mirage detection was used to determine the thermal conductivity of various thin films deposited on semiconductor substrates. The first type consisted of conducting oxide films: ZnO and CdO deposited on GaSb:Te, while the other contained high dielectric constant HfO(2) layers on Si. All films were fabricated using a magnetron sputtering technique.
View Article and Find Full Text PDFWe report on the theoretical analysis of a detector type influence on the normal deflection signal in photothermal experiments. Two cases are examined. In the first, the quadrant photodiode was considered as the detector; in the second the signal from the position detector, which measures the central moment displacement of the probe beam, was analyzed.
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