Higher Temperatures Yield Smaller Grains in a Thermally Stable Phase-Transforming Nanocrystalline Alloy.

Grains in crystalline materials usually grow with increased thermal exposure. Classical phenomena such as recrystallization may lead to a purely temporary decrease in the grain size, while recent advances in alloy design can yield thermally stable nanocrystalline materials in which grain growth stagnates. But grains never shrink, since there is a lack of interface-generating mechanisms at high temperatures, which are required to decrease the grain size if such was the system's thermodynamic tendency.

Core(Fe)-shell(Au) nanoparticles obtained from thin Fe/Au bilayers employing surface segregation.

Core(Fe)-shell(Au) nanoparticles are obtained by solid-state dewetting of thin Fe/Au bilayer films deposited on a sapphire substrate. The core-shell morphology is achieved by employing the equilibrium segregation phenomenon, where Au atoms form a homogeneous thin shell on the surfaces of an Fe nanoparticle and at its interface with the substrate, reducing the total interfacial energy of the system. The obtained nanoparticles are single crystalline (structurally perfect), thermally stable, and of high purity.