Influences of Propofol, Ciprofol and Remimazolam on Dreaming During Anesthesia for Gastrointestinal Endoscopy: A Randomized Double-Blind Parallel-Design Trial.

Purpose: To compare the influences of propofol, ciprofol and remimazolam on dreaming during painless gastrointestinal endoscopy.

Methods: This study was a single-center, prospective, parallel-design, double-blind, randomized clinical trial. Between May 2023 and October 2023, patients undergoing elective painless gastrointestinal endoscopy were recruited and randomly allocated into one of the three groups.

Dielectric and Wavefunction Engineering of Electron Spin Lifetime in Colloidal Nanoplatelet Heterostructures.

Colloidal semiconductor nanoplatelets (NPLs) have emerged as low-cost and free-standing alternates of traditional quantum wells. The giant heavy- and light-hole splitting in NPLs allows for efficient optical spin injection. However, the electron spin lifetimes for prototypical CdSe NPLs are within a few picoseconds, likely limited by strong electron-hole exchange in these quantum- and dielectric-confined materials.

Heterojunction photocatalyst FeS/g-CN for activating sulfites to degrade tetracycline: A stable degradation system based on heterogeneous processes.

The UV/sulfite system is a promising source of •SO and/or •OH, but its application is largely limited by the use of UV light due to its high cost and high energy consumption. Graphite carbon nitride (g-CN), as a new photocatalytic material, has better visible light absorption capacity and narrower band gap than g-CN, which is expected to activate sulfite under visible light to solve this problem. Herein, a novel FeS/CN heterojunction material based on g-CN was constructed by hydrothermal in-situ synthesis method and successfully activated sulfite, which was confirmed by tetracycline degradation experiments in water.

Scrutinizing the interaction between metribuzin with glutathione reductase 2 from Arabidopsis thaliana: insight into the molecular toxicity in agriculture.

As one of the triazine herbicides with widespread usage in agriculture, metribuzin exerted nonnegligible hazardous effects on plants via excessive accumulation of reactive oxygen species and destruction of antioxidant enzymes, but the underlying harmful mechanism of metribuzin-induced oxidative damage to plants has never been exploited. Here, Arabidopsis thaliana glutathione reductase 2 (AtGR2) was employed as the biomarker to evaluate the adverse impacts of metribuzin on plants. The fluorescence intensity of AtGR2 was decreased based on the static quenching mechanism with the prediction of a single binding site toward metribuzin, and the complex formation was presumed to be mainly impelled by hydrogen bonding and van der Waals forces from the negative ΔH and ΔS.

Colloidal -Doped CdSe and CdSe/ZnS Nanoplatelets.

Colloidal semiconductor nanoplatelets (NPLs) are chemical versions of well-studied quantum wells (QWs). For QWs, gating and carrier doping are standard tools to manipulate their optical, electric, or magnetic properties. It would be highly desirable to use pure chemical methods to dope extra charge carriers into free-standing colloidal NPLs to achieve a similar level of manipulation.

Exploring the toxic interactions between Bisphenol A and glutathione peroxidase 6 from Arabidopsis thaliana.

As primary industrial raw material, the widespread usage of bisphenol A (BPA) has resulted in sustained release and accumulation in the environment. Besides its endocrine-disrupting character, BPA was reported to generate excessive reactive oxygen species (ROS). However, the potential toxic mechanisms of the BPA-induced oxidative damage to plants were poorly understood.

Spin blockade and phonon bottleneck for hot electron relaxation observed in n-doped colloidal quantum dots.

Understanding and manipulating hot electron dynamics in semiconductors may enable disruptive energy conversion schemes. Hot electrons in bulk semiconductors usually relax via electron-phonon scattering on a sub-picosecond timescale. Quantum-confined semiconductors such as quantum dots offer a unique platform to prolong hot electron lifetime through their size-tunable electronic structures.

Electron and Hole Spin Relaxation in CdSe Colloidal Nanoplatelets.

Solution-processed quantum-confined nanocrystals are important building blocks for scalable implementation of quantum information science. Extensive studies on colloidal quantum dots (QDs) have revealed subpicosecond hole spin relaxation, whereas the electron spin dynamics remains difficult to probe. Here we study electron and hole spin dynamics in CdSe colloidal nanoplatelets (also called quantum wells) of varying thicknesses using circularly polarized transient absorption spectroscopy at room temperature.

CO2 reduction catalyzed by mercaptopteridine on glassy carbon.

The catalytic reduction of CO2 is of great current interest because of its role in climate change and the energy cycle. We report a pterin electrocatalyst, 6,7-dimethyl-4-hydroxy-2-mercaptopteridine (PTE), that catalyzes the reduction of CO2 and formic acid on a glassy carbon electrode. Pterins are natural cofactors for a wide range of enzymes, functioning as redox mediators and C1 carriers, but they have not been exploited as electrocatalysts.

A non-intermetallic PtPb/C catalyst of hollow structure with high activity and stability for electrooxidation of formic acid.

A non-intermetallic PtPb/C catalyst of hollow structure is synthesized through a simple reduction method, and exhibits an activity as high as 3.6 times that of commercial Pd black and a much higher stability for electrooxidation of formic acid.