ACS Appl Mater Interfaces
October 2024
Hierarchical superstructures, ubiquitously found in nature, offer enhanced efficiency in both substance reaction and mass transport owing to their unique multiscale features. Inspired by these natural systems, this research reports a general and scalable electrochemical scheme for creating highly branched, multilevel porous superstructures on various electrically conductive substrates. These structures exhibit cascading features from centimeters, submillimeters, micrometers, down to sub-100 nm, significantly increasing the surface area of substrates, such as foams, foils, and carbon cloth by 2 orders of magnitude─among the highest reported enhancements.
View Article and Find Full Text PDFSwarming, a phenomenon widely present in nature, is a hallmark of nonequilibrium living systems that harness external energy into collective locomotion. The creation and study of manmade swarms may provide insights into their biological counterparts and shed light to the rules of life. Here, we propose an innovative mechanism for rationally creating multimodal swarms with unprecedented spatial, temporal, and mode control.
View Article and Find Full Text PDFOwing to Brownian-motion effects, the precise manipulation of individual micro- and nanoparticles in solution is challenging. Therefore, scanning-probe-based techniques, such as atomic force microscopy, attach particles to cantilevers to enable their use as nanoprobes. Here we demonstrate a versatile electrokinetic trap that simultaneously controls the two-dimensional position with a precision of 20 nm and 0.
View Article and Find Full Text PDFEasy access to clean water is essential to functioning and development of modern society. However, it remains arduous to develop energy-efficient, facile, and portable water treatment systems for point-of-use (POU) applications, which is particularly imperative for the safety and resilience of society during extreme weather and critical situations. Here, we propose and validate a meritorious working scheme for water disinfection via directly capturing and removing pathogen cells from bulk water using strategically designed three-dimensional (3D) porous dendritic graphite foams (PDGFs) in a high-frequency AC field.
View Article and Find Full Text PDFSubwavelength optical resonators with spatiotemporal control of light are essential to the miniaturization of optical devices. In this work, chemically synthesized transition metal dichalcogenide (TMDC) nanowires are exploited as a new type of dielectric nanoresonators to simultaneously support pronounced excitonic and Mie resonances. Strong light-matter couplings and tunable exciton polaritons in individual nanowires are demonstrated.
View Article and Find Full Text PDF2D transition-metal-dichalcogenide materials, such as molybdenum disulfide (MoS ) have received immense interest owing to their remarkable structure-endowed electronic, catalytic, and mechanical properties for applications in optoelectronics, energy storage, and wearable devices. However, 2D materials have been rarely explored in the field of micro/nanomachines, motors, and robots. Here, MoS with anatase TiO is successfully integrated into an original one-side-open hollow micromachine, which demonstrates increased light absorption of TiO -based micromachines to the visible region and the first observed motion acceleration in response to ionic media.
View Article and Find Full Text PDFDynamic acoustic wavefront control is essential for many acoustic applications, including biomedical imaging and particle manipulation. Conventional methods are either static or in the case of phased transducer arrays are limited to a few elements and hence limited control. Here, a dynamic acoustic wavefront control method based on light patterns that locally trigger the generation of microbubbles is introduced.
View Article and Find Full Text PDFMechanically programmable, reconfigurable micro/nanoscale materials that can dynamically change their mechanical properties or behaviors, or morph into distinct assemblies or swarms in response to stimuli have greatly piqued the interest of the science community due to their unprecedented potentials in both fundamental research and technological applications. To date, a variety of designs of hard and soft materials, as well as actuation schemes based on mechanisms including chemical reactions and magnetic, acoustic, optical, and electric stimuli, have been reported. Herein, state-of-the-art micro/nanostructures and operation schemes for multimodal reconfigurable micro/nanomachines and swarms, as well as potential new materials and working principles, challenges, and future perspectives are discussed.
View Article and Find Full Text PDFMolybdenum disulfide (MoS ) is a multifunctional material that can be used for various applications. In the single-crystalline form, MoS shows superior electronic properties. It is also an exceptionally useful nanomaterial in its polycrystalline form with applications in catalysis, energy storage, water treatment, and gas sensing.
View Article and Find Full Text PDFTo develop active nanomaterials that can instantly respond to external stimuli with designed mechanical motions is an important step towards the realization of nanorobots. Herein, we present our finding of a versatile working mechanism that allows instantaneous change of alignment direction and speed of semiconductor nanowires in an external electric field with simple visible-light exposure. The light induced alignment switch can be cycled over hundreds of times and programmed to express words in Morse code.
View Article and Find Full Text PDFSolar steaming has emerged as a promising green technology that can address the global issue of scarcity of clean water. However, developing high-performance, cost-effective, and manufacturable solar-steaming materials, and portable solar steaming-collection systems for individuals remains a great challenge. Here, a one-step, low-cost, and mass-producible synthesis of polypyrrole (PPy) origami-based photothermal materials, and an original portable low-pressure controlled solar steaming-collection unisystem, offering synergetic high rates in both water evaporation and steam collection, are reported.
View Article and Find Full Text PDFIn this work, we report an innovative type of rotary biomicromachines by using diatom frustules as integrated active components, including the assembling, operation, and performance characterization. We further investigate and demonstrate unique applications of the biomicromachines in achieving individually reconfigurable micromachine arrays and microfluidic mixing. Diatom frustules are porous cell walls of diatoms made of silica.
View Article and Find Full Text PDFIn this study, we investigated the control of the rotation dynamics of an innovative type of rotary micromotors with desired performances by tuning the magnetic interactions among the assembled micro/nanoscale components. The micromotors are made of metallic nanowires as rotors, patterned magnetic nanodisks as bearings and actuated by external electric fields. The magnetic forces for anchoring the rotors on the bearings play an essential role in the rotation dynamics of the micromotors.
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