ACS Appl Mater Interfaces
December 2023
Kesterite CuZnSn(S,Se) (CZTSSe) has been considered as the most promising absorber material for inorganic thin-film solar cells. Among the three main interfaces in CZTSSe-based solar cells, the CZTSSe/Mo back interface plays an essential role in hole extraction as well as device performance. During the selenization process, the reaction between CZTSSe and Mo is one of the main reasons that lead to a large open circuit voltage () deficit, low short circuit current (), and fill factor.
View Article and Find Full Text PDFThe main bottleneck in the development of kesterite CuZnSn(S,Se) (CZTSSe) solar cells is their very low due to severe carrier recombination. Specifically, due to the poor defect environment and unfavorable band structure, carrier recombination at the front interface is considered to be one of the most serious issues. Thus, to reduce the interface recombination and deficit, we propose a convenient and effective strategy for Cd gradient doping near the front interface during selenization.
View Article and Find Full Text PDFIn this study, ZnO nanotubes (ZNTs) were prepared onto fluorine-doped tin oxide (FTO) glass and used as supports for MIPs arrays fabrication. Due to the imprinted cavities are always located at both inner and outer surface of ZNTs, these ZNTs supported MIPs arrays have good accessibility towards template and can be used as sensing materials for chemical sensors with high sensitivity, excellent selectivity and fast response. Using K[Fe(CN)] as electron probe, the fabricated electrochemical sensor shows two linear dynamic ranges (0.
View Article and Find Full Text PDFp-type inorganic hole transport materials of Li, Cu-codoped NiOx films were deposited using a simple solution-based process. The as-prepared films were used as hole selective contacts for lead halide perovskite solar cell. An enhanced power conversion efficiency of 14.
View Article and Find Full Text PDFCZTS exhibited apparently phase-dependent photocatalytic H2 evolution under visible light. Possible factors for the phase-dependent photocatalytic activity of CZTS were discussed in detail.
View Article and Find Full Text PDFIn this work, we employed a convenient one-step synthesis method for synthesizing Cu2ZnSnSe4 (CZTSe) nanocrystals (NCs) in an excess selenium environment. This excess selenium situation enhanced the reaction of metal acetylacetonates with selenium, resulting in the burst nucleation of NCs at relatively low temperatures. The phase morphology and surface and optoelectronic properties of NCs before and after ligand exchange were discussed in depth.
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