In order to investigate the energy transfer mechanism and the nonequilibrium effect during water evaporation in its own pure vapor at low pressures, a series of precise measurements are conducted to obtain the temperature profile near the liquid-vapor interface and the evaporation rates in an annular pool in a closed chamber. The results show that the interface temperature of the vapor side is higher than that of the liquid side when water evaporates in its own pure vapor at low pressures (ranging from 394 to 1467 Pa), the temperature discontinuity across the interface exists in all experimental conditions. The magnitude of the temperature discontinuity is strongly affected by the vapor pressure.
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