Discrimination of metal contaminant sources in river sediments influenced by mining and smelting activities using stable Pb and Zn isotopes.

To determine the sources and pathways of lead (Pb) and zinc (Zn) in river sediments contaminated with metals from mining and smelting activities, metal concentrations and Pb and Zn isotope ratios were measured in river water and sediment, and potential metal contaminant samples (imported Zn concentrates, smelting wastes, soils around the smelter, mine ores, and riverside tailings). Zn and cadmium (Cd) concentrations in river water and sediment samples were 30- and 11-25-fold higher, respectively, near the smelter than upstream, while a 6-fold increase in sediment Pb concentrations was detected over the same region. Sediment samples near the smelter (Pb/Pb = 0.

Mercury contamination of sediments in an open coastal area of the Hupo Basin, East Sea, Korea.

Mercury (Hg) contamination in open coastal areas has attracted public concern regarding safe fish consumption and management of the coastal environment, especially in areas of accidental Hg spills on inland coasts. This study investigated the temporal and spatial distribution of Hg in sediments of Youngil Bay and the Hupo Basin, East Sea, Korea; it also discussed the sources and transport of anthropogenic Hg. Hg hot spots were found in the northern Hupo Basin (elevated by 2-3×) and the river mouth area in Youngil Bay (elevated by approximately 70×).