In the title calcium levulinate complex, [Ca(C5H7O3)2(H2O)2] n , the Ca(2+) ion lies on a twofold rotation axis and is octa-coordinated by two aqua ligands and six O atoms from four symmetry-related carboxyl-ate ligands, giving a distorted square-anti-prismatic coordination stereochemistry [Ca-O bond-length range = 2.355 (1)-2.599 (1) Å].
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