ACS Appl Mater Interfaces
February 2019
Solid electrolytes are the key to realize future solid-state batteries that show the advantages of high energy density and intrinsic safety. However, most solid electrolytes require long time and energy-consuming synthesis conditions of either extended ball milling or high-temperature solid-state reactions, impeding practical applications of solid electrolytes for large-scale systems. Here, we report a new and rapid liquid-based synthetic method for preparing a high-purity LiPS solid electrolyte through the stoichemical reaction of LiPS and LiS.
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View Article and Find Full Text PDFWe describe the coupled straintronic-photothermic effect where coupling between bandgap of the 2D layered semiconductor under localized strains, optical absorption and the photo-thermal effect results in a large chromatic mechanical response in TMD-nanocomposites. Under the irradiation of visible light (405 nm to 808 nm), such locally strained atomic thin films based on 2H-MoS embedded in an elastomer such as poly (dimethyl) siloxane matrix exhibited a large amplitude of photo-thermal actuation compared to their unstrained counterparts. Moreover, the locally strain engineered nanocomposites showed tunable mechanical response giving rise to higher mechanical stress at lower photon energies.
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View Article and Find Full Text PDFThe ability to convert electrical energy into mechanical motion is of significant interest in many energy conversion technologies. Here, we demonstrate the first liquid phase exfoliated WS-Nafion nanocomposite based electro-mechanical actuators. Highly exfoliated layers of WS mixed with Nafion solution, solution cast and doped with Li was studied as electromechanical actuators.
View Article and Find Full Text PDFThe ability to convert photons of different wavelengths directly into mechanical motion is of significant interest in many energy conversion and reconfigurable technologies. Here, using few layer 2H-MoS nanosheets, layer by layer process of nanocomposite fabrication, and strain engineering, we demonstrate a reversible and chromatic mechanical response in MoS-nanocomposites between 405 nm to 808 nm with large stress release. The chromatic mechanical response originates from the d orbitals and is related to the strength of the direct exciton resonance A and B of the few layer 2H-MoS affecting optical absorption and subsequent mechanical response of the nanocomposite.
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