ZnO tetrapod morphology influence on UV sensing properties.

The aim of this work was to investigate how ZnO tetrapod (ZnO-T) morphology, structure, and surface charge properties (i.e. Debye length) influence their UV sensing properties, shedding light on the underlying photoresponse mechanisms.

Combined DFT-D3 Computational and Experimental Studies on g-CN: New Insight into Structure, Optical, and Vibrational Properties.

Graphitic carbon nitride (g-CN) has emerged as one of the most promising solar-light-activated polymeric metal-free semiconductor photocatalysts due to its thermal physicochemical stability but also its characteristics of environmentally friendly and sustainable material. Despite the challenging properties of g-CN, its photocatalytic performance is still limited by the low surface area, together with the fast charge recombination phenomena. Hence, many efforts have been focused on overcoming these drawbacks by controlling and improving the synthesis methods.

From gaseous HCN to nucleobases at the cosmic silicate dust surface: an experimental insight into the onset of prebiotic chemistry in space.

HCN in the gas form is considered as a primary nitrogen source for the synthesis of prebiotic molecules in extraterrestrial environments. Nevertheless, the research mainly focused on the reactivity of HCN and its derivatives in aqueous systems, often using external high-energy supply in the form of cosmic rays or high energy photons. Very few studies have been devoted to the chemistry of HCN in the gas phase or at the gas/solid interphase, although they represent the more common scenarios in the outer space.

Graphene and Other 2D Layered Nanomaterials and Hybrid Structures: Synthesis, Properties and Applications.

The field of two-dimensional (2D) layered nanomaterials, their hybrid structures, and composite materials has been suddenly increasing since 2004, when graphene-almost certainly the most known 2D material-was successfully obtained from graphite via mechanical exfoliation [...

Thermal, Morphological, Electrical Properties and Touch-Sensor Application of Conductive Carbon Black-Filled Polyamide Composites.

Polyamide 66 (PA66) is a well-known engineering thermoplastic polymer, primarily employed in polymer composites with fillers and additives of different nature and dimensionality (1D, 2D and 3D) used as alternatives to metals in various technological applications. In this work, carbon black (CB), a conductive nanofiller, was used to reinforce the PA66 polymer in the 9-27 wt. % CB loading range.

Multifunctional Conductive Paths Obtained by Laser Processing of Non-Conductive Carbon Nanotube/Polypropylene Composites.

Functional materials are promising candidates for application in structural health monitoring/self-healing composites, wearable systems (smart textiles), robotics, and next-generation electronics. Any improvement in these topics would be of great relevance to industry, environment, and global needs for energy sustainability. Taking into consideration all these aspects, low-cost fabrication of electrical functionalities on the outer surface of carbon-nanotube/polypropylene composites is presented in this paper.

Effect of Injection Molding Conditions on Crystalline Structure and Electrical Resistivity of PP/MWCNT Nanocomposites.

Polypropylene (PP) / multi-walled carbon nanotube (MWCNT) nanocomposites were prepared by melt-mixing and used to manufacture samples by injection molding. The effect of processing conditions on the crystallinity and electrical resistivity was studied. Accordingly, samples were produced varying the mold temperature and injection rate, and the DC electrical resistivity was measured.

Polyserine repeats promote coiled coil-mediated fibril formation and length-dependent protein aggregation.

Short polyserine (polyS) repeats are frequently found in proteins and longer ones are produced in neurological disorders such as Huntington disease (HD) owing to translational frameshifting or non-ATG-dependent translation, together with polyglutamine (polyQ) and polyalanine (polyA) repeats, forming intracellular aggregates. However, the physiological and pathological structures of polyS repeats are not clearly understood. Early studies highlighted their structural versatility, similar to other homopolymers whose conformation is influenced by the surrounding protein context.

From biowaste to magnet-responsive materials for water remediation from polycyclic aromatic hydrocarbons.

Composted urban biowaste-derived substances (BBS-GC) are used as carbon sources for the preparation of carbon-coated magnet-sensitive nanoparticles obtained via co-precipitation method and the subsequent thermal treatment at 550 °C under nitrogen atmosphere. A multitechnique approach has been applied to investigate the morphology, magnetic properties, phase composition, thermal stability of the obtained magnet-sensitive materials. In particular, pyrolysis-induced modifications affecting the BBS-GC/carbon shell were highlighted.

Few-Layer MoS₂ Nanodomains Decorating TiO₂ Nanoparticles: A Case Study for the Photodegradation of Carbamazepine.

S-doped TiO₂ and hybrid MoS₂/TiO₂ systems have been synthesized, via the sulfidation with H₂S of the bare TiO₂ and of MoO supported on TiO₂ systems, with the aim of enhancing the photocatalytic properties of TiO₂ for the degradation of carbamazepine, an anticonvulsant drug, whose residues and metabolites are usually inefficiently removed in wastewater treatment plants. The focus of this study is to find a relationship between the morphology/structure/surface properties and photoactivity. The full characterization of samples reveals the strong effects of the H₂S action on the properties of TiO₂, with the formation of defects at the surface, as shown by transmission electron microscopy (TEM) and infrared spectroscopy (IR), while also the optical properties are strongly affected by the sulfidation treatment, with changes in the electronic states of TiO₂.

Carbon Domains on MoS/TiO System via Catalytic Acetylene Oligomerization: Synthesis, Structure, and Surface Properties.

Carbon domains have been obtained at the surface of a MoS/TiO (Evonik, P25) system via oligomerization and cyclotrimerization reactions involved in the interaction of the photoactive material with acetylene. Firstly, MoS nanosheets have been synthesized at the surface of TiO, via sulfidation of a molybdenum oxide precursor with HS (bottom-up method). Secondly, the morphology and the structure, the optical and the vibrational properties of the obtained materials, for each step of the synthesis procedure, have been investigated by microscopy and spectroscopy methods.

Resonance Raman and IR spectroscopy of aligned carbon nanotube arrays with extremely narrow diameters prepared with molecular catalysts on steel substrates.

Carbon nanotubes (CNTs) are considered promising for a large range of emerging technologies ranging from advanced electronics to utilization as nanoreactors. Here we report a controlled facile synthesis of aligned carbon nanotubes with very small dimensions directly grown on steel grid substrates via two-step catalytic chemical vapor deposition (CCVD) of a molecular catalyst (ferrocene) with ethylene as the carbon source. The system is characterized by resonance Raman spectroscopy and the results show single walled carbon nanotube (SWCNT) arrays composed of 0.

MoS2 Nanoparticles Decorating Titanate-Nanotube Surfaces: Combined Microscopy, Spectroscopy, and Catalytic Studies.

MoS2/TNTs composites have been obtained by impregnation of titanate nanotubes (TNTs) with a centrifuged solution of nanosized MoS2 particles in isopropyl alcohol (IPA). The characterization has been performed by combining UV-vis-NIR, Raman, AFM, and HRTEM analyses, before and after impregnation. HRTEM images show that the contact between single-layer MoS2 nanoparticles and the support is efficient, so justifying the decoration concept.

Thickness of multiwalled carbon nanotubes affects their lung toxicity.

Two samples of highly pure multiwalled carbon nanotubes (MWCNTs) similar in hydrophobicity and surface reactivity were prepared with similar length, <5 μm, but markedly different diameter (9.4 vs 70 nm). The samples were compared for their cytotoxic activity, uptake, and ability to induce oxidative stress (ROS production and intracellular GSH depletion) in vitro in murine alveolar macrophages (MH-S).

Altered excitability of cultured chromaffin cells following exposure to multi-walled carbon nanotubes.

We studied the effects of multi-walled carbon nanotubes (MWCNTs) on the electrophysiological properties of cultured mouse chromaffin cells, a model of spontaneously firing cells. The exposure of chromaffin cells to MWCNTs at increasing concentrations (30-263 μg/ml) for 24 h reduced, in a dose-dependent way, both the cell membrane input resistance and the number of spontaneously active cells (from 80-52%). Active cells that survived from the toxic effects of MWCNTs exhibited more positive resting potentials, higher firing frequencies and unaltered voltage-gated Ca(2+), Na(+) and K+ current amplitudes.

(I(2))(n) encapsulation inside TiO(2): a way to tune photoactivity in the visible region.

We report on the synthesis of nanovoid-structured TiO(2) material via a sol-gel route using titanium isopropoxide as precursor. The nanovoids are formed during the thermal treatment in air at 773 K. The surfaces of internal cavities are populated by the partial oxidation products of the organic part of the Ti precursor (CO(2), hydrogen carbonates, and residual isopropoxide groups).

Cu+(H2) and Na+(H2) adducts in exchanged ZSM-5 zeolites.

Cu(I) ions in Cu-ZSM-5 form Cu+(H2) complexes, stable at room temperature and sub-atmospheric H2 pressure, which do not have any homogeneous analogue except for matrix-isolated [Cu(eta2-H2)Cl]. Comparison with the unstable Na+(H2) adducts formed in the parent Na-ZSM-5 zeolite allow the conclusion that the Cu(I)/H2 bond is governed by sigma-pi overlap forces.