Towards sustainable electrochemistry: green synthesis and sintering aid modulations in the development of BaZrYMO (M = Mn, Co, and Fe) IT-SOFC electrolytes.

In this study, BaZrYMO perovskite electrolytes with sintering aids (M = Mn, Co, and Fe) were synthesized by a sustainable approach using spinach powder as a chelating agent and then compared with chemically synthesized BaZrYMO (M = Mn, Co, and Fe) electrolytes for intermediate temperature SOFCs. This is the first example of such a sustainable synthesis of perovskite materials with sintering aids. Structural analysis revealed the presence of a cubic perovskite structure in BaZrYMO (M = Mn, Co, and Fe) samples synthesized by both green and conventional chemical methods.

Divergent karyotypes in five genera of the African endemic fish family Distichodontidae (Cithariniformes, Osteichthyes).

The African family Distichodontidae comprises 109 species in 16 genera. Up-to-date cytogenetic information was available for the only distichodontid species Günther, 1873. Here we report chromosome number and morphology in: Günther, 1864 (2n = 52, FN = 104), (Joannis, 1835) (2n = 46, FN = 92), (Joannis, 1835) (2n = 54, FN = 106) and three taxa, Géry et Zarske, 2003, sp.

First cytogenetic data on Afrotropical lutefishes (Citharinidae) in the light of karyotype evolution in Characiformes.

The Afrotropical lutefish family Citharinidae (Citharinoidei, Characiformes) comprises three genera with eight species in total. Although Citharinidae have been studied in terms of taxonomy and systematics, no cytogenetic information was available for any representative of the family. Furthermore, only one species out of 116 in Citharinoidei ( Günther, 1873) has been studied cytogenetically.

Modernized Synthesis Technique of PrNiO-Based Complex Oxides Using Low-Temperature Salt Melts.

Phases based on layered lanthanide nickelates are considered as promising electrode materials for various electrochemical devices, including solid oxide fuel cells and electrolysis cells. While such compounds may be prepared using either solid state or solution-assisted syntheses, each of these approaches entails certain problems. In the present work, we propose a novel approach for the simple and straightforward preparation of PrNiO-based materials.

Nickel-Containing Perovskites, PrNiFeO and PrNiCoO, as Potential Electrodes for Protonic Ceramic Electrochemical Cells.

Protonic ceramic fuel cells (PCFCs) offer a convenient means of converting chemical energy into electricity with high performance and efficiency at low- and intermediate-temperature ranges. However, in order to ensure good life-time stability of PCFCs, it is necessary to ensure rational chemical design in functional materials. Within the present work, we propose new Ni-based perovskite phases of PrNiMO (where M = Co, Fe) for potential utilization in protonic ceramic electrochemical cells.

Layered Oxygen-Deficient Double Perovskites as Promising Cathode Materials for Solid Oxide Fuel Cells.

Development of new functional materials with improved characteristics for solid oxide fuel cells (SOFCs) and solid oxide electrolysis cells (SOECs) is one of the most important tasks of modern materials science. High electrocatalytic activity in oxygen reduction reactions (ORR), chemical and thermomechanical compatibility with solid electrolytes, as well as stability at elevated temperatures are the most important requirements for cathode materials utilized in SOFCs. Layered oxygen-deficient double perovskites possess the complex of the above-mentioned properties, being one of the most promising cathode materials operating at intermediate temperatures.

Description of a new species of the genus Verhoeff, 1917 and redescription of Borutzky, 1957 from the southeast of European Russia (Isopoda, Oniscidea, Agnaridae).

A new species of woodlice, Gongalsky & Turbanov, is described from Kalmykia, NE Pre-Caspian region, Russia. Borutzky, 1957 from the same area is also redescribed. Diagnostic features of these species as well as affinities within the genus are provided and discussed.

Thermal lattice Boltzmann method for multiphase flows.

An alternative method to simulate heat transport in the multiphase lattice Boltzmann (LB) method is proposed. To solve the energy transport equation when phase boundaries are present, the method of a passive scalar is considerably modified. The internal energy is represented by an additional set of distribution functions, which evolve according to an LB-like equation simulating the transport of a passive scalar.

Anisotropic instability of a dielectric liquid in a strong uniform electric field: Decay into a two-phase system of vapor filaments in a liquid.

The linear stability analysis of dielectric liquid placed in uniform electric field with respect to perturbations of density of an initially uniform state was carried out. The electric field increases the instability increment for the stratification along the field and decreases it for the transversal stratification. Thus, anisotropic separation into liquid and vapor phases is possible in high electric fields for a liquid that is initially in unstable state, as well as in metastable or stable states.