Novel metal-organic framework hydrogel for enhanced selective removal of uranyl ions from nuclear wastewater.

The efficient removal of uranium (U(Ⅵ)) from nuclear wastewater presents a significant challenge due to the high concentrations of uranium and various interfering ions. In this study, we developed and used metal-organic framework hydrogel (MOFH) as a highly efficient adsorbent for uranium removal. The MOFH, synthesized with ferrocyanides and functional groups (Fe(Ⅱ)-CN-Fe(Ⅲ), OH, -COOH, and -NH), exhibited good chemical stability, large separation capacity, and high selectivity.

Enhanced cadmium removal by a magnetic potassium ferrocyanide framework: Performance and mechanism study.

Polluted environments often contain large amounts of toxic metals, such as cadmium, which pose a major threat to ecosystems and public health. Contamination by cadmium and its compounds is often observed in areas surrounding zinc mining sites and electroplating factories, and the control of cadmium pollution is essential for environmental safety and health. In this study, a highly efficient and straightforward separation strategy for KFe(CN)@FeO nanocomposites is successfully developed to capture the Cd ions in the water environment.

Stabilization of Uranium in Acid Ore Wastewater through Hydrothermal Mineralization-Induced Crystallization.

Uranium [U(VI)] mining activity resulted in the discharge of uranium containing acid wastewater. It is necessary for immobilizing the uranium from wastewater to avoid its environmental pollution. In this work, a novel hydrothermal mineralization strategy is proposed for uranium stabilization.

Novel biocompatible N-rich AIE fluorescent probe for live cell imaging and visual onsite detection of uranium.

A sensitive and biocompatible N-rich probe for rapid visual uranium detection was constructed by grafting two trianiline groups to 2,6-bis(aminomethyl)pyridine. Possessing excellent aggregation-induced emission (AIE) property and the advantages to form multidentate chelate with U selectively, the probe has been applied successfully to visualize uranium in complex environmental water samples and living cells, demonstrating outstanding anti-interference ability against large equivalent of different ions over a wide effective pH range. A large linear range (1.

Risk assessment and strontium isotopic tracing of potentially toxic metals in creek sediments around a uranium mine, China.

The contamination of creek sediments near industrially nuclear dominated site presents significant environmental challenges, particularly in identifying and quantifying potentially toxic metal (loid)s (PTMs). This study aims to measure the extent of contamination and apportion related sources for nine PTMs in alpine creek sediments near a typical uranium tailing dam from China, including strontium (Sr), rubidium (Rb), manganese (Mn), lithium (Li), nickel (Ni), copper (Cu), vanadium (V), cadmium (Cd), zinc (Zn), using multivariate statistical approach and Sr isotopic compositions. The results show varying degrees of contamination in the sediments for some PTMs, i.

Microbial features with uranium pollution in artificial reservoir sediments at different depths under drought stress.

The uranium (U) containing leachate from uranium tailings dam into the natural settings, may greatly affect the downstream environment. To reveal such relationship between uranium contamination and microbial communities in the most affected downstream environment under drought stress, a 180 cm downstream artificial reservoir depth sediment profile was collected, and the microbial communities and related genes were analyzed by 16S rDNA and metagenomics. Besides, the sequential extraction scheme was employed to shed light on the distinct role of U geochemical speciations in shaping microbial community structures.

Distribution and migration of uranium, chromium, and accompanying metal(loid)s in soil-plants system around a uranium hydrometallurgical area.

The extraction and utilization of uranium (U) ores have led to the release of significant amounts of potentially toxic metal(loid)s (PTMs) into the environment, constituting a grave threat to the ecosystem. However, research on the distribution and migration mechanism of U, chromium (Cr), and their accompanying PTMs in soil-plant system around U hydrometallurgical area remains insufficient and poorly understood. Herein, the distribution, migration, and risk level of PTMs were evaluated in soil and plant samples around U hydrometallurgical area, Northern Guangdong, China.

Transfer, transportation, and adsorption of UV-B by Mg-N co doped carbon quantum dots: Response of growth indicators, antioxidant effect and mechanism explanation.

Mg and N co-doped carbon quantum dots (Mg-N-CQDs) were synthesized and applied to alleviate oxygen toxicity by UV-B radiation and enhance antioxidative responses to wheat seedlings. It showed that Mg-N-CQDs pre-treatment attenuated the UV-B stress effects in a dose-dependent manner, as indicated by enhancing the characteristics of seed germination and early seedling growth parameters. Meanwhile, Mg-N-CQDs can be applied in plant nutrient solutions with nitrogen, phosphorus, potassium, and other fertilizers to promote the growth of seedlings.

Uranium recovery from weakly acidic wastewater using recyclable γ-FeO@meso-SiO.

U(VI)-containing acidic wastewater produced from uranium mining sites is an environmental hazard. Highly efficient capture of U(VI) from such wastewater is of great significance. In this study, a mesoporous core-shell material (i.

Statistically and visually analyzing the latest advancements and future trends of uranium removal.

Uranium contamination and remediation is a very important environmental research area. Removing radioactive and toxic uranium from contaminated media requires fundamental knowledge of targets and materials. To explore the-State-of-the-Art in uranium contamination control, we employed a statistical tool called CiteSpace to visualize and statistically analyze 4203 peer-reviewed papers on uranium treatment published between 2008 and 2022.

Release and mobility characteristics of thallium from polluted farmland in varying fertilization: Role of cation exchange.

Batch and column leaching tests were used to study thallium's release and migration behaviour and evaluate its potential toxicity risks in soil. The results indicated that leaching concentrations of Tl using TCLP and SWLP were much higher than the threshold, indicating a high risk of thallium pollution in the soil. Furthermore, the intermittent leaching rate of Tl by Ca and HCl reached its maximum value, demonstrating the easy release of Tl.

Fabrication of highly efficient hydroxyapatite microtubes for uranium sequestration and immobilization.

Uranium-containing wastewater is a common by-product of uranium mining. Phosphate and phosphate minerals can interact with uranyl ions [U(VI)], impeding the migration of these ions by forming relatively stable uranium-containing crystalline phase(s). In this study, hydroxyapatite microtubes (HAP-T) were fabricated to sequester uranyl ions from simulated radioactive wastewater.

High yielded Co-C derived from polyester-Cobalt carbothermal reduction for efficient activation of peroxymonosulfate to degrade levofloxacin.

A kind of high yield and recyclable Cobalt-Carbon composite (ZnCo/PC) was prepared by carbothermal reduction process, in which the cobalt acetate and zinc acetate were considered as Zn and Co precursors, and the polyester waste was evolved as the carbon precursor. The morphology, structure and composition of the composite were characterized using scanning electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy. Results showed that evaporation of zinc contributed to the formation of porous carbon structure, and the Co nanoparticles were wrapped and protected by the porous carbon matrix.

Reply to the comments on "Facilely synthesized cobalt doped hydroxyapatite as hydroxyl promoted peroxymonosulfate activator for degradation of Rhodamine B" by Zuo et al.

In a Co-HAP/PMS system, catalytic degradation process of RhB was accompanied by the gradual leaching of cobalt ion. The results of additional experiments showed that leached cobalt ion indeed contributed to active PMS for RhB degradation, which was not addressed in the previous study. The finding of the contribution from leached cobalt ion to PMS activation was reported due to the valuable comments of Zuo et al.

"Two-in-one" dual-function luminescent MOF hydrogel for onsite ultra-sensitive detection and efficient enrichment of radioactive uranium in water.

In consideration of the severe hazards of radioactive uranium pollution and the growing demand of uranium resources, the novel sensor/adsorbent composite was creatively developed to integrate the dual functions for on-site detection of uranium contamination and efficient recovery of uranium resources. By hybridizing the luminescent 3D terbium (III) metal-organic framework (Tb-MOF) with sodium alginate (SA) gel using terbium (III) as cross-linker, the Tb-MOF/Tb-AG was fabricated with multi-luminescence centers and sufficient binding sites for uranium. Notably, the ultra-high sensitivity with detection limit as low as 1.

The latest research trends in the removal of cesium from radioactive wastewater: A review based on data-driven and visual analysis.

The widespread adoption of nuclear energy has increased the amount of radioactive cesium (Cs) that is discharged into waste streams, which can have environmental risks. In this paper, we provide a comprehensive summary of current advances in aqueous Cs removal by employing a bibliometric analysis. We collected 1580 articles related to aqueous Cs treatment that were published on the Web of Science database between 2012 and 2022.

Hidden risks from potentially toxic metal(loid)s in paddy soils-rice and source apportionment using lead isotopes: A case study from China.

Pyrite is a typical sulfide mineral which contains various potentially toxic metal(loid)s (PTMs). The pyrite smelting and subsequent industrial utilization activities usually release numerous amounts of PTMs into nearby ecosystem, which may be enriched in the nearby farmland soils and crops, leading to hidden but irreversible harm to human health via the food chain. Herein, the distribution pattern, source apportionment, and potential health risks of Pb, Zn, Cu, Cd and multiple seldom monitored PTMs (Ag, Bi, Sb, Sr, Th, U, W, and V) in the paddy soils and different organs of the rice plants from ten various sites in a typical industrial zone were investigated, where pyrite ores were used for the production of sulfuric acid and subsequent cement over several decades.

Highly selective adsorption and lattice process of cesium by cubic cyanide-based functional materials.

Cesium (Cs) is a byproduct of nuclear bombs, nuclear weapons testing, and nuclear fission in nuclear reactors. Cs can enter the human body through food or air and cause lasting damage. Highly efficient and selective removal of Cs from low-level radioactive effluents (LLREs), which contain many radionuclides and dissolved heavy metal species, is imperative for minimizing LLRE volume, and facilitating their final disposal.

Effectiveness and mechanism of uranium adsorption on size-graded red mud.

As a type of useful solid waste, red mud (RM) should be reused to achieve waste-to-resource strategies. Additionally, the fast development of nuclear industry requires effective and reliable materials for treating uranium (U)-containing wastewater. This study attempted to remove uranyl ions [U(VI)] from mimic radioactive wastewater by various RM particles with different size fractions (e.

Highly-efficient and easy separation of γ-FeO selectively adsorbs U(Ⅵ) in waters.

The migration and transformation of uranyl [U (Ⅵ)] ions in the environment are quite dependent on the geological condition in particular with the site enriched in Fe. In this study, the interfacial interaction of U (Ⅵ) ions with maghemite (γ-FeO) particles was studied and the interaction mechanism was explored as well. Batch experiments confirm that γ-FeO can effectively remove U (Ⅵ) from an aqueous solution within a relatively short reaction time (R% > 92.

U(VI) adsorption by green and facilely modified Ficus microcarpa aerial roots: Behavior and mechanism investigation.

Uranium (U)-containing wastewater poses serious pressure to human health and environmental safety. The treatment of U-bearing wastewater using green and facilely fabricated materials is considered a promising alternative. Herein, the raw and modified aerial roots of Ficus microcarpa (RARF and MARF, respectively) were prepared and applied to the treatment of synthesized U-containing wastewater.

Phosphate enhanced uranium stable immobilization on biochar supported nano zero valent iron.

Uranium (U) immobilization from wastewater by zero valent iron (ZVI) was widely concerned through reduction and surface adsorption. Releasing of U due to re-oxidation of U(IV) into U(VI) limited the application of ZVI in U decontamination. In this work, a kind of biochar supported nano zero valent iron (Fe/BC(900)) was obtained by carbothermal reduction of starch mixed with ferric nitrate at 900 °C.

Dual light-driven p-ZnFeO/n-TiO catalyst: Benzene-breaking reaction for malachite green.

Heterocyclic aromatic compounds such as malachite green can cause immense harm to the environment and mankind because of their toxic bio-accumulation and insufficient biodegradation. ZnFeO/TiO (ZF-T) has attracted attentions as a visible-light-driven catalyst because it can break and mineralize benzene through photolysis. Compared with TiO, which photodegrades only 53.

Synthesis of thickness-controllable polydopamine modified halloysite nanotubes (HNTs@PDA) for uranium (VI) removal.

Halloysite nanotubes (HNTs) are considered structurally promising adsorption materials, but their application is limited due to their poor native adsorption properties. Improving the adsorption capacity of HNTs for radioactive U(VI) is of great significance. By controlling the mass ratio of HNTs and dopamine (DA), composite adsorbents (HNTs@PDA) with different polydopamine (PDA) layer thicknesses were synthesized.