Advancing interactive systems with liquid crystal network-based adaptive electronics.

Achieving adaptive behavior in artificial systems, analogous to living organisms, has been a long-standing goal in electronics and materials science. Efforts to integrate adaptive capabilities into synthetic electronics traditionally involved a typical architecture comprising of sensors, an external controller, and actuators constructed from multiple materials. However, challenges arise when attempting to unite these three components into a single entity capable of independently coping with dynamic environments.

Photoresponsive Biomimetic Functions by Light-Driven Molecular Motors in Three Dimensionally Printed Liquid Crystal Elastomers.

Despite the fascinating developments in design and synthesis of artificial molecular machines operating at the nanoscales, translating molecular motion along multiple length scales and inducing mechanical motion of a three-dimensional macroscopic entity remains an important challenge. The key to addressing this amplification of motion relies on the effective organization of molecular machines in a well-defined environment. By taking advantage of long-range orientational order and hierarchical structures of liquid crystals and unidirectional rotation of light-driven molecular motors, we report here photoresponsive biomimetic functions of liquid crystal elastomers (LCEs) by the repetitive unidirectional rotation of molecular motors using 3D printing.

Transforming patterned defects into dynamic poly-regional topographies in liquid crystal oligomers.

We create high-aspect-ratio dynamic poly-regional surface topographies in a coating of a main-chain liquid crystal oligomer network (LCON). The topographies form at the topological defects in the director pattern organized in an array which are controlled by photopatterning of the alignment layer. The defect regions are activated by heat and/or light irradiation to form reversible topographic structures.

Facilitating Interskin Communication in Artificial Polymer Systems through Liquid Transfer.

Chemical communication is a ubiquitous process in nature, and it has sparked interest in the development of electric-sense-based robotic perception systems with chemical components. Here, a novel liquid crystal polymer is introduced that combines the transferring, receiving, and sensing of chemical signals, providing a new principle to achieve chemical communication in robotic systems. This approach allows for the transfer of cargo between two polymer coatings, and the transfer can be monitored through an electrical signal.

A cold-responsive liquid crystal elastomer provides visual signals for monitoring a critical temperature decrease.

Critical temperature indicators have been extensively utilized in various fields, ranging from healthcare to food safety. However, the majority of the temperature indicators are designed for upper critical temperature monitoring, indicating when the temperature rises and exceeds a predefined limit, whereas stringently demanded low critical temperature indicators are scarcely developed. Herein, we develop a new material and system that monitor temperature decrease, , from ambient temperature to the freezing point, or even to an ultra-low temperature of -20 °C.

Reversible Perspiring Artificial "Fingertips".

Fingertip perspiration is a vital process within human predation, to which the species owes its survival and its biological success. In this paper, the unique human ability of extensive perspiration and controlled friction in self-assembled cholesteric liquid crystals is recreated, mimicking the natural processes that occur in the dermis and epidermis of human skin. This is achieved by inducing porosity in responsive, liquid-bearing material through the controlled-polymerization phase-separation process.

Perspiring Soft Robotics Skin Constituted by Dynamic Polarity-Switching Porous Liquid Crystal Membrane.

Secretion of functional fluids is essential for affecting surface properties in ecosystems. The existing polymer membranes that mimic human skin functions are limited to secreting, either apolar or polar, liquid. However, the development of membranes that grant exchange liquid with different polarities remains a grand challenge.

Facile Stratification-Enabled Emergent Hyper-Reflectivity in Cholesteric Liquid Crystals.

Cholesteric liquid crystals (CLCs) are chiral photonic materials with selective reflection in terms of wavelength and polarization. Helix engineering is often required in order to produce desired properties for CLC materials to be employed for beam steering, light diffraction, scattering, and adaptive or broadband reflection. Here, we demonstrate a novel photopolymerization-enforced stratification (PES)-based strategy to realize helix engineering in a chiral CLC system with initially one handedness of molecular rotation throughout the layer.

Photo-responsive liquid crystal network-based material with adaptive modulus for haptic application.

Artificially created tactile feedback is in high demand due to fast developments in robotics, remote control in medicine, virtual reality, and smart electronics. Despite significant progress, high-quality haptic feedback devices remain challenging mainly due to the lack of stability and spatiotemporal resolution. In this work, we address these issues by the application of dynamic coatings, based on photo-responsive liquid crystal network (LCN) material.

Light- and Field-Controlled Diffusion, Ejection, Flow and Collection of Liquid at a Nanoporous Liquid Crystal Membrane.

Liquid manipulation at solid surfaces has attracted plenty of interest yet most of them are limited to one or two direction(s), while transport in three dimensions is largely unexplored. Here, we demonstrate three-dimensionally steered dynamic liquid mobility at nanoporous liquid crystal polymer coatings. To this end, we orchestrate liquid motion via sequential triggers of light and/or electric field.

Biomimetic Liquid Crystal Cilia and Flagella.

Cilia and flagella are a vital part of many organisms. Protozoa such as paramecia rely on the collective and coordinated beating of tubular cilia or flagella for their transport, while mammals depend on the ciliated linings of their bronchia and female reproductive tracts for the continuity of breathing and reproduction, respectively. Over the years, man has attempted to mimic these natural cilia using synthetic materials such as elastomers doped with magnetic particles or light responsive liquid crystal networks.

Phototriggered Complex Motion by Programmable Construction of Light-Driven Molecular Motors in Liquid Crystal Networks.

Recent developments in artificial molecular machines have enabled precisely controlled molecular motion, which allows several distinct mechanical operations at the nanoscale. However, harnessing and amplifying molecular motion along multiple length scales to induce macroscopic motion are still major challenges and comprise an important next step toward future actuators and soft robotics. The key to addressing this challenge relies on effective integration of synthetic molecular machines in a hierarchically aligned structure so numerous individual molecular motions can be collected in a cooperative way and amplified to higher length scales and eventually lead to macroscopic motion.

Photo-Imprinting of the Helical Organization in Liquid-Crystal Networks Using Achiral Monomers and Circularly Polarized Light.

Control over molecular motion is facilitated in materials with highly ordered nanoscale structures. Here we report on the fabrication of cholesteric liquid-crystal networks by circularly polarized light irradiation, without the need for chiral dopant or plasticizer. The polymer network is obtained by photopolymerization of a smectic achiral diacrylate mesogen consisting of an azobenzene core and discrete oligodimethylsiloxane tails.

Versatile homeotropic liquid crystal alignment with tunable functionality prepared by one-step method.

Alignment layers are vital to the function of numerous devices based on liquid crystal (LC) materials. The pursue of versatile, effective and even flexible alignment layers, preferably prepared by simple methods, is still actively ongoing. Herein, we propose a facile one-step method by mixing silanes into the starting LC mixtures, which in contact with a glass substrate secede and self-assemble in-situ to form a stable and highly effective homeotropic alignment layer at the interface.

Nano-Second Laser Interference Photoembossed Microstructures for Enhanced Cell Alignment.

Photoembossing is a powerful photolithographic technique to prepare surface relief structures relying on polymerization-induced diffusion in a solventless development step. Conveniently, surface patterns are formed by two or more interfering laser beams without the need for a lithographic mask. The use of nanosecond pulsed light-based interference lithography strengthens the pattern resolution through the absence of vibrational line pattern distortions.

Programmed topographical features generated on command in confined electroactive films.

This work describes a method to create dynamic pre-programmed surface textures by an alternating electric field on coatings that consist of a silicon oxide reinforced viscoelastic siloxane network. The finite element method is developed to predict the complex deformation figures and time-resolved experimental topographical surface analysis is used to confirm them.

Translating 2D Director Profile to 3D Topography in a Liquid Crystal Polymer.

Morphological properties of surfaces play a key role in natural and man-made objects. The development of robust methods to fabricate micro/nano surface structures has been a long pursuit. Herein, an approach based on molecular self-assembling of liquid crystal polymers (LCPs) is presented to directly translate 2D molecular director profiles obtained by a photoalignment procedure into 3D topographies, without involving further multi-step lithographic processes.

Photoswitching between Water-Tolerant Adhesion and Swift Release by Inverting Liquid Crystal Fingerprint Topography.

Although switchable adhesive surfaces are important and desirable for soft robotics, it is still challenging to replicate nature's switchable adhesion capability on artificial surfaces, especially for underwater applications. Here polymeric coatings with fingerprint topographies that are capable of switching the surface adhesion upon light illumination are reported. This is achieved via a synergistic combination of surface topographical inversion and spatially selective distribution of adhesive polymers.

Coupled liquid crystalline oscillators in Huygens' synchrony.

In the flourishing field of soft robotics, strategies to embody communication and collective motion are scarce. Here we report the synchronized oscillations of thin plastic actuators by an approach reminiscent of the synchronized motion of pendula and metronomes. Two liquid crystalline network oscillators fuelled by light influence the movement of one another and display synchronized oscillations in-phase and anti-phase in a steady state.

Photo-responsive Helical Motion by Light-Driven Molecular Motors in a Liquid-Crystal Network.

Controlling sophisticated motion by molecular motors is a major goal on the road to future actuators and soft robotics. Taking inspiration from biological motility and mechanical functions common to artificial machines, responsive small molecules have been used to achieve macroscopic effects, however, translating molecular movement along length scales to precisely defined linear, twisting and rotary motions remain particularly challenging. Here, we present the design, synthesis and functioning of liquid-crystal network (LCN) materials with intrinsic rotary motors that allow the conversion of light energy into reversible helical motion.

Consequences of Chirality in Directing the Pathway of Cholesteric Helix Inversion of π-Conjugated Polymers by Light.

Control over main-chain motion of chiral π-conjugated polymers can lead to unexpected new functionalities. Here, it is shown that by combining photoswitchable azobenzene units in conjugation with chiral fluorene comonomers and appropriate plasticizers, the polymer organization and chiroptical properties of these alternating copolymers steered by light and its state of polarization can be dynamically controlled. The configuration of the stereogenic centers in the side chains of the fluorene units determines the handedness of the cholesteric organization in thermally annealed films, indicating cooperative behavior.

Magnetic Resonance Monitoring of Opaque Temperature-Sensitive Polymeric Scaffolds.

The monitoring of location and degradation rates of injectable biomaterials is an area of particular interest in the design and implementation of therapeutic scaffolds and carriers for tissue repair and replacement. We describe here the fabrication and characterization of gadolinium (Gd)-labeled temperature-responsive hydrogels that can be detected noninvasively using -weight magnetic resonance. Two acrylamide-functionalized GdDOTA-monoamide complexes with either a short -butylene spacer (Gd-C4-AA) or a long hydrophilic spacer (Gd-PEG-AA) were synthesized and incorporated into the hydrogels.

Artificial Organic Skin Wets Its Surface by Field-Induced Liquid Secretion.

Living organisms enhance their survival rate by excreting fluids at their surface, but man-made materials can also benefit from liquid secretion from a solid surface. Known approaches to secrete a liquid from solids are limited to passive release driven by diffusion, surface tension, or pressure. Remotely triggered release would give active control over surface properties but is still exceptional.